A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering†
Yan-Zhen Zheng Dr.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorMing-Liang Tong Prof. Dr.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorWei Xue
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorWei-Xiong Zhang
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorXiao-Ming Chen Prof. Dr.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorFernande Grandjean Prof. Dr.
Department of Physics, B5, Université de Liège, 4000 Sart-Tilman, Belgium
Search for more papers by this authorGary J. Long Prof. Dr.
Department of Chemistry, University of Missouri-Rolla, Rolla, MO 65409-0010, USA, Fax: (+1) 573-341-6033
Search for more papers by this authorYan-Zhen Zheng Dr.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorMing-Liang Tong Prof. Dr.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorWei Xue
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorWei-Xiong Zhang
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorXiao-Ming Chen Prof. Dr.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorFernande Grandjean Prof. Dr.
Department of Physics, B5, Université de Liège, 4000 Sart-Tilman, Belgium
Search for more papers by this authorGary J. Long Prof. Dr.
Department of Chemistry, University of Missouri-Rolla, Rolla, MO 65409-0010, USA, Fax: (+1) 573-341-6033
Search for more papers by this authorThis work was supported by the NSFC (grant no. 20531070), the Science and Technology Department of Guangdong Province (grant no. 04205405), and the National Fund for Scientific Research, Belgium (grant no. 1.5.064.05).
Graphical Abstract
Star formation: Polymeric [Fe3(μ3-O)(μ-OAc)6(H2O)3][Fe3(μ3-O)μ-OAc)7.5]2⋅7 H2O is synthesized by linking triangular {Fe3(μ3-O)} clusters through anti-anti bridging acetate ligands (see picture; red and blue: Fe, orange: O). Spin frustration and long-range magnetic order coexist in this compound below 4.5 K (see graph).
Supporting Information
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