Ordered Mesoporous Polymers and Homologous Carbon Frameworks: Amphiphilic Surfactant Templating and Direct Transformation†
Yan Meng
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorDong Gu
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorFuqiang Zhang
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorYifeng Shi
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorHaifeng Yang Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorZheng Li
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorChengzhong Yu Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorBo Tu Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorDongyuan Zhao Prof. Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorYan Meng
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorDong Gu
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorFuqiang Zhang
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorYifeng Shi
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorHaifeng Yang Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorZheng Li
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorChengzhong Yu Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorBo Tu Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorDongyuan Zhao Prof. Dr.
Department of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
Search for more papers by this authorThis work was supported by the NSF of China (20233030 and 20421303), the State Key Basic Research Program of PRC (G200048001, 2001CB610506), Project 863 of the Sci. & Tech Ministry of China (2002 AA321010), the Shanghai Sci. & Tech. Committee (03J14004, 02A14005, 03527001, 04JC14087), LG Company, Unilever Research China, and the Shanghai HuaYi Chemical Group. We thank Dr. T. C. Li, S. H. Xie, and Dr. Y. Wan for experimental and characterization assistance.
Graphical Abstract
Ultrahigh stability (>1400 °C) is found for the highly ordered mesoporous polymers and carbon frameworks synthesized from polymerization of phenol and formaldehyde around triblock copolymer templates. Calcination and carbonization lead to removal of the templates and formation of hexagonal and cubic carbon mesostructures with large uniform pores and surface areas (see schematic diagram).
Supporting Information
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