Review
In the Golden Age of Organocatalysis†
Peter I. Dalko Dr.,
Lionel Moisan,
Peter I. Dalko Dr.
Laboratoire de Recherches Organiques associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05, France, Fax: (+33) 1-4079-4660
Search for more papers by this authorLionel Moisan
CEA-SACLAY, Service de Marquage Moléculaire et de Chimie Bioorganique, Bât 547, 91191 Gif-sur-Yvette Cedex, France
Search for more papers by this authorPeter I. Dalko Dr.,
Lionel Moisan,
Peter I. Dalko Dr.
Laboratoire de Recherches Organiques associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05, France, Fax: (+33) 1-4079-4660
Search for more papers by this authorLionel Moisan
CEA-SACLAY, Service de Marquage Moléculaire et de Chimie Bioorganique, Bât 547, 91191 Gif-sur-Yvette Cedex, France
Search for more papers by this author†
The illustration on the frontispiece is taken from the codex The Book of Chess, Dice, and Board Games, completed around 1280 by Alfonso X of Castille. Alfonso's heritage represents above all a great cultural bridge between the Christian West and the Muslim East. In a similar way, organocatalysis represents a link between two major forms of catalysis: metal-complex-mediated and enzymatic catalysis, and thus between synthetic and bioorganic chemistry.
Graphical Abstract
Metal-free synthesis: An increasing number of asymmetric organic reactions can be catalyzed by a chiral organic molecule. Although substrate dependency remains an important issue in many cases, a large number of organocatalytic transformations are as efficient as current standards in asymmetric synthesis demand (see example).
Abstract
The term “organocatalysis” describes the acceleration of chemical reactions through the addition of a substoichiometric quantity of an organic compound. The interest in this field has increased spectacularly in the last few years as result of both the novelty of the concept and, more importantly, the fact that the efficiency and selectivity of many organocatalytic reactions meet the standards of established organic reactions. Organocatalytic reactions are becoming powerful tools in the construction of complex molecular skeletons. The diverse examples show that in recent years organocatalysis has developed within organic chemistry into its own subdiscipline, whose “Golden Age” has already dawned.
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Citing Literature
