Fully Optical Control of Polarization Current Direction in a Cyanide-Bridged Trinuclear Complex
Yu-Bo Huang
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Sheng-Qun Su
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorWen-Huang Xu
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorWen-Wei Zheng
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorKai-Ge Gao
College of Physical Science and Technology, Yangzhou University, Jiangsu, 225009 P. R. China
Search for more papers by this authorTian-Chi Ji
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorXiao-Peng Zhang
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorQi-Rui Shui
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorZi-Qi Zhou
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorTaisuke Ikeda
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Shu-Qi Wu
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Prof. Osamu Sato
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorYu-Bo Huang
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Sheng-Qun Su
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorWen-Huang Xu
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorWen-Wei Zheng
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorKai-Ge Gao
College of Physical Science and Technology, Yangzhou University, Jiangsu, 225009 P. R. China
Search for more papers by this authorTian-Chi Ji
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorXiao-Peng Zhang
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorQi-Rui Shui
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorZi-Qi Zhou
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorTaisuke Ikeda
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Shu-Qi Wu
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Prof. Osamu Sato
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorAbstract
As a remote and non-contact stimulus, light offers the potential for manipulating the polarization of ferroelectric materials without physical contact. However, in current research, the non-contact write-read (erase) process lacks direct observation through the stable current as output signal. To address this limitation, we investigated the photoinduced polarization switching capabilities of the cyanide-bridged compound [Fe2Co] using visible light, leading to the achievement of rewritable polarization. By subjecting [Fe2Co] crystals to alternating irradiation with 785 nm and 532 nm light, the polarization changes exhibited a distinct square wave pattern, confirming the reliability of the writing and erasing processes. Initialization involved exposing specific crystal units to 532 nm light for storing “1” or “0” information, while reading was accomplished by scanning the units with 785 nm light, resulting in brief current pulses for “1” states and no current signal for “0” states. This research unveils new possibilities for optical storage systems, paving the way for efficient and rewritable data storage and retrieval technologies, such as the next-generation memories.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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