Volume 135, Issue 35 e202308990
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Innenrücktitelbild: Integrated Soft Porosity and Electrical Properties of Conductive-on-Insulating Metal-Organic Framework Nanocrystals (Angew. Chem. 35/2023)

Prof. Ming-Shui Yao

Prof. Ming-Shui Yao

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Zhongguancun Beiertiao No. 1, Haidian District, Beijing, 100190 China

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Chinese Academy of Sciences, No.19(A) Yuquan Road, Shijingshan District, Beijing, 100049 China

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Prof. Ken-ichi Otake

Corresponding Author

Prof. Ken-ichi Otake

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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Jiajia Zheng

Jiajia Zheng

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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Masahiko Tsujimoto

Masahiko Tsujimoto

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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Dr. Yi-Fan Gu

Dr. Yi-Fan Gu

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Road 1239, Shanghai, 200092 China

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Lu Zheng

Lu Zheng

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Siping Road 1239, Shanghai, 200092 China

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Dr. Ping Wang

Dr. Ping Wang

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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Dr. Shivanna Mohana

Dr. Shivanna Mohana

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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Dr. Mickaele Bonneau

Dr. Mickaele Bonneau

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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Tomoyuki Koganezawa

Tomoyuki Koganezawa

Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 Japan

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Tetsuo Honma

Tetsuo Honma

Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 Japan

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Hirotaka Ashitani

Hirotaka Ashitani

Department of Physical Science, Graduate School of Science, Osaka Prefecture University, Osaka, Japan

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Shogo Kawaguchi

Shogo Kawaguchi

Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 Japan

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Prof. Yoshiki Kubota

Prof. Yoshiki Kubota

Department of Physical Science, Graduate School of Science, Osaka Prefecture University, Osaka, Japan

Department of Physics, Graduate School of Science, Osaka Metropolitan University, Osaka, Japan

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Prof. Susumu Kitagawa

Corresponding Author

Prof. Susumu Kitagawa

Institute for Integrated Cell-Material Sciences, Kyoto University, Institute for Advanced Study, Kyoto University, Yoshida, Ushinomiya-cho, Sakyo-ku, Kyoto, 606-8501 Japan

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First published: 14 July 2023

Graphical Abstract

Conductive-on-insulating metal–organic framework (cMOF-on-iMOF) heterostructured nanocrystals are reported by Ken-ichi Otake, Susumu Kitagawa et al. in their Research Article (e202303903). These nanocrystals combine soft porosity and electrical properties into a single material. They exhibit semiconductive soft porous interfaces that connect a flexible core and a chemiresistive shell. The cMOF-on-iMOF nanocrystals demonstrate enhanced selective sorption towards CO2, as well as readable softness, electrical gating, and shape memory effects for the guest-responsive iMOF core.

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