2,2′-Biphenol-based Ultrathin Microporous Nanofilms for Highly Efficient Molecular Sieving Separation
Prof. Shao-Lu Li
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorGuoliang Chang
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorYangzheng Huang
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorKen Kinooka
Research Center for Membrane and Film Technology, Graduate School of Science, Technology and Innovation, Kobe University, Kobe, 657-8501 Japan
Search for more papers by this authorYanting Chen
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorWenming Fu
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Genghao Gong
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorProf. Tomohisa Yoshioka
Research Center for Membrane and Film Technology, Graduate School of Science, Technology and Innovation, Kobe University, Kobe, 657-8501 Japan
Search for more papers by this authorCorresponding Author
Prof. Neil B. McKeown
EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, EH9 3FJ UK
Search for more papers by this authorCorresponding Author
Prof. Yunxia Hu
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorProf. Shao-Lu Li
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorGuoliang Chang
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorYangzheng Huang
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorKen Kinooka
Research Center for Membrane and Film Technology, Graduate School of Science, Technology and Innovation, Kobe University, Kobe, 657-8501 Japan
Search for more papers by this authorYanting Chen
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorWenming Fu
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Genghao Gong
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorProf. Tomohisa Yoshioka
Research Center for Membrane and Film Technology, Graduate School of Science, Technology and Innovation, Kobe University, Kobe, 657-8501 Japan
Search for more papers by this authorCorresponding Author
Prof. Neil B. McKeown
EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, EH9 3FJ UK
Search for more papers by this authorCorresponding Author
Prof. Yunxia Hu
State Key Laboratory of Separation Membranes and Membrane Processes, School of Materials Science and Engineering, Tiangong University, Tianjin, 300387, P.R. China Tianjin 300387 P.R. China
Search for more papers by this authorAbstract
Organic solvent nanofiltration (OSN) is an emerging membrane separation technology, which urgently requires robust, easily processed, OSN membranes possessing high permeance and small solutes-selectivity to facilitate enhanced industrial uptake. Herein, we describe the use of two 2,2′-biphenol (BIPOL) derivatives to fabricate hyper-crosslinked, microporous polymer nanofilms through IP. Ultra-thin, defect-free polyesteramide/polyester nanofilms (≈5 nm) could be obtained readily due to the relatively large molecular size and ionized nature of the BIPOL monomers retarding the rate of the IP. The enhanced microporosity arises from the hyper-crosslinked network structure and monomer rigidity. Specifically, the amino-BIPOL/PAN membrane exhibits extraordinary permselectivity performances with molecular weight cut-off as low as 233 Da and MeOH permeance of ≈13 LMH/bar. Precise separation of small dye mixtures with similar M.W. based on both their charge and molecular size are achieved.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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