Experimental Detection of Trinitramide, N(NO2)3†
Corresponding Author
Dr. Martin Rahm
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Competence Centre for Energetic Materials (KCEM), Gammelbackavägen 6, 69151 Karlskoga (Sweden)
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207Search for more papers by this authorDr. Sergey V. Dvinskikh
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Search for more papers by this authorProf. István Furó
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Search for more papers by this authorCorresponding Author
Prof. Tore Brinck
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207Search for more papers by this authorCorresponding Author
Dr. Martin Rahm
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Competence Centre for Energetic Materials (KCEM), Gammelbackavägen 6, 69151 Karlskoga (Sweden)
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207Search for more papers by this authorDr. Sergey V. Dvinskikh
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Search for more papers by this authorProf. István Furó
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Search for more papers by this authorCorresponding Author
Prof. Tore Brinck
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm (Sweden), Fax: (+46) 8-790-8207Search for more papers by this authorWe gratefully acknowledge support given by the Swedish Research Council (VR), the Swedish Defence Research Agency (FOI), and Eurenco Bofors. Exselent and the Knut and Alice Wallenberg foundation are thanked for the IR equipment. Michael Holmboe, Madeleine Warner, and Henrik Skifs are thanked for their kind assistance.
Graphical Abstract
Treibstoff in Propellerform: Das bislang größte Stickstoffoxid, Trinitramid (TNA), wurde IR- und NMR-spektroskopisch nachgewiesen, nachdem in quantenchemischen Studien seine kinetische Beständigkeit und einige physikalische Eigenschaften vorhergesagt worden waren. Die Verbindung ist außerordentlich energiereich und möglicherweise als kryogener Treibstoff und zur Erforschung von Materialien mit hoher Energiedichte geeignet.
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