Hydrogen Chloride†
Gary W. Breton
University of North Carolina, Chapel Hill, NC, USA
Search for more papers by this authorPaul J. Kropp
University of North Carolina, Chapel Hill, NC, USA
Search for more papers by this authorGary W. Breton
University of North Carolina, Chapel Hill, NC, USA
Search for more papers by this authorPaul J. Kropp
University of North Carolina, Chapel Hill, NC, USA
Search for more papers by this authorAbstract
[7647-01-0] ClH (MW 36.46)
InChI = 1S/ClH/h1H
InChIKey = VEXZGXHMUGYJMC-UHFFFAOYSA-N
(reagent for hydrochlorination of alkenes and alkynes;4 cleaves epoxides1b and ethers;21a converts alcohols to chlorides12b and diols to cyclic ethers;17 chloroalkylates arenes;22 converts aldehydes to α-chloro ethers23b)
Alternate Name: Hydrochloric Acid
Solubility: sol most organic solvents.2
Form Supplied in: widely available; compressed gas; 1 M solution in AcOH, Et2O, or Me2S; 4 M solution in dioxane; 37% aqueous solution.
Preparative Methods: addition of H2SO4 to NaCl or 37% aqueous HCl.3
Handling, Storage, and Precautions: highly toxic and corrosive; handle only in a fume hood.
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