Allyltriphenylstannane - Koreeda - Major Reference Works - Wiley Online Library

(widely used allylating agent as an allyl anion equivalent directly or by transmetalating to other allylmetals,^{2, 3} radical chain transfer reagent, and source of allyl radical⁴)

Alternate Names: allyltriphenyltin; (2-propenyl)triphenylstan-nane.

Physical Data: mp 73–74 °C (recryst. from ligroin).⁵

Solubility: sol THF, methylene chloride, chloroform, and benzene.

Form Supplied in: white solid in over 97% purity (microanalysis).

Analysis of Reagent Purity: CH microanalysis, IR,⁶ ¹H,⁷ or ¹³C NMR spectroscopy.

Handling, Storage, and Precautions: poison by intravenous route; ivn-mus LD₅₀: 100 mg kg⁻¹;⁸ no significant reactivity with aqueous systems. Use in a fume hood.

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