Volume 60, Issue 5 pp. m703-m704

Tetra-μ-acetato-κ8O:O′-bis­[(2-benzyl­idene-6,7-di­hydro-5H-thia­zolo­[3,2-a]pyrimidin-3-one-κN)­cobalt(II)]

First published: 14 May 2004
Xun Li, e-mail: [email protected]

Abstract

The title compound, [Co2(C2H3O2)4(C13H12N2OS)2], is a binuclear complex, which occupies a special position at an inversion centre. Each Co atom has a distorted octahedral coordination, which involves four O atoms of four μ-acetate groups [Co—O = 1.9617 (19)–1.977 (2) Å] and the N atom of the 2-benzyl­idene-6,7-di­hydro-5H-thia­zolo­[3,2-a]­pyrimidin-3-one ligand [Co—N = 2.214 (2) Å]; the coordination octahedron is completed by the Co—Co bond of 2.6708 (8) Å.

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