2,2′,2′′-Nitrilotris(ethylammonium) tris(pyridine-2,6-dicarboxylato-κ3O,N,O′)terbate(III) hexahydrate
Abstract
The asymmetric unit of the title compound, (C6H21N4)[Tb(C7H3NO4)3]·6H2O, consists of a (C6H21N4)3+ cation, and a [(C7H3NO4)3Tb]3− anion, and six molecules of water. In the anion, three pyridine-2,6-dicarboxylate ligands are coordinated to the TbIII atom via the N atom of the pyridine ring and two O atoms of different carboxylate groups. The coordination polyhedron around Tb may be described as a pseudo-tricapped trigonal prism. The crystal packing is stabilized by electrostatic interactions and intermolecular hydrogen bonds involving the cation, anion and water molecules.