Volume 58, Issue 11 pp. m666-m668

2,2′,2′′-Nitrilo­tris­(ethyl­ammonium) tris­(pyridine-2,6-di­carboxyl­ato-κ3O,N,O′)­terbate(III) hexahydrate

First published: 29 July 2004
Citations: 1
Chun-Gu Xia, e-mail: [email protected]

Abstract

The asymmetric unit of the title compound, (C6H21N4)[Tb(C7H3NO4)3]·6H2O, consists of a (C6H21N4)3+ cation, and a [(C7H3NO4)3Tb]3− anion, and six molecules of water. In the anion, three pyridine-2,6-di­carboxyl­ate ligands are coordinated to the TbIII atom via the N atom of the pyridine ring and two O atoms of different carboxyl­ate groups. The coordination polyhedron around Tb may be described as a pseudo-tricapped trigonal prism. The crystal packing is stabilized by electrostatic interactions and intermolecular hydrogen bonds involving the cation, anion and water mol­ecules.

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