Volume 58, Issue 11 pp. m611-m612

Bis­(di­cyclo­hexyl­ammonium) tungstate dihydrate, [NH2(C6H11)2]2[WO4]·2H2O

Wenhua Bi

Wenhua Bi

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China

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Daofeng Sun

Daofeng Sun

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China

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Rong Cao

Rong Cao

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China

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Jiutong Chen

Jiutong Chen

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China

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Maochun Hong

Maochun Hong

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China

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First published: 29 July 2004
Rong Cao, e-mail: [email protected]

Abstract

The crystal structure of the title complex is built of di­cyclo­hexyl­ammonium cations, [NH2(C6H11)2]+, orthotungstate dianions, [WO4]2−, and lattice water mol­ecules. The cations and coordinated water mol­ecules occupy special positions on twofold axes; the tetrahedral orthotungstate dianion is located on a axis. Hydrogen bonds involving all N- and O-bound H atoms link the cations, anions and water mol­ecules into an infinite three-dimensional aggregate. The crystal is isostructural with its molybdenum analog [Thiele & Fuchs (1979). Z. Naturforsch. Teil B, 34, 145–154].

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