Volume 58, Issue 3 pp. m110-m112

A cluster containing a pyrazole ligand: [Ru3(μ-H)(μ-N2C3H3)(CO)10]

Enrique Lozano Diz

Enrique Lozano Diz

Institut de Chimie, Université de Neuchâtel, Case postale 2, CH-2007 Neuchâtel, Switzerland

Search for more papers by this author
Antonia Neels

Antonia Neels

Institut de Chimie, Université de Neuchâtel, Case postale 2, CH-2007 Neuchâtel, Switzerland

Search for more papers by this author
Bruno Therrien

Bruno Therrien

Institut de Chimie, Université de Neuchâtel, Case postale 2, CH-2007 Neuchâtel, Switzerland

Search for more papers by this author
Helen Stoeckli-Evans

Helen Stoeckli-Evans

Institut de Chimie, Université de Neuchâtel, Case postale 2, CH-2007 Neuchâtel, Switzerland

Search for more papers by this author
Georg Süss-Fink

Georg Süss-Fink

Institut de Chimie, Université de Neuchâtel, Case postale 2, CH-2007 Neuchâtel, Switzerland

Search for more papers by this author
First published: 29 July 2004
Bruno Therrien, e-mail: [email protected]

Abstract

The title cluster deca­carbonyl-1κ4C,2κ3C,3κ3C-μ-hydrido-2:3κ2­H:H-μ-pyrazolyl-2:3κ2N1:N2-triangulo-triruthenium, (I), [Ru3(μ-H)(μ-C3H3N2)(CO)10], which contains a pyrazole ligand, has been synthesized and characterized, both spectroscopically and crystalographically, as a cyclohexane solvate. The molecular structure of (I) is very similar to that of the known di­methyl­pyrazole derivative [Ru3(μ-H){μ-N2C3H(CH3)2-3,5}(CO)10].

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.