Volume 57, Issue 4 pp. 354-355

Dichloro(2,2′-diamino-4,4′-bi-1,3-thiazole-N3,N3′)copper(II)

First published: 23 June 2004
Duan-Jun Xu, e-mail: [email protected]

Abstract

The title complex, [CuCl2(C6H6N4S2)], has a flattened tetrahedral coordination. The CuII atom is located on a twofold rotation axis and is coordinated by two N atoms from a chelating 2,2′-di­amino-4,4′-bi-1,3-thia­zole ligand and by two Cl atoms. Intramolecular hydrogen bonding exists between the amino groups of the 2,2′-di­amino-4,4′-bi-1,3-thia­zole ligand and the Cl atoms. The intermolecular separation of 3.425 (1) Å between parallel bi­thia­zole rings suggests there is a π–π interaction between them.

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