Dichloro(2,2′-diamino-4,4′-bi-1,3-thiazole-N3,N3′)copper(II)
Abstract
The title complex, [CuCl2(C6H6N4S2)], has a flattened tetrahedral coordination. The CuII atom is located on a twofold rotation axis and is coordinated by two N atoms from a chelating 2,2′-diamino-4,4′-bi-1,3-thiazole ligand and by two Cl atoms. Intramolecular hydrogen bonding exists between the amino groups of the 2,2′-diamino-4,4′-bi-1,3-thiazole ligand and the Cl atoms. The intermolecular separation of 3.425 (1) Å between parallel bithiazole rings suggests there is a π–π interaction between them.