(Cyclopentadienyl)trioxorhenium(VII) – no Match for Methyltrioxorhenium (MTO)†
Manuel Högerl
Munich / Germany, Technische Universität München, Department Chemie, Molecular Catalysis
Search for more papers by this authorCorresponding Author
Fritz E. Kühn Prof.
Munich / Germany, Technische Universität München, Department Chemie, Molecular Catalysis
Department Chemie, Technische Universität München, Lichtenbergstr. 4, D-85747 Garching bei München / Germany, Fax: 0049 (0)89 289 13473Search for more papers by this authorManuel Högerl
Munich / Germany, Technische Universität München, Department Chemie, Molecular Catalysis
Search for more papers by this authorCorresponding Author
Fritz E. Kühn Prof.
Munich / Germany, Technische Universität München, Department Chemie, Molecular Catalysis
Department Chemie, Technische Universität München, Lichtenbergstr. 4, D-85747 Garching bei München / Germany, Fax: 0049 (0)89 289 13473Search for more papers by this authorDedicated to Professor Heinrich Nöth on the Occasion of his 80th Birthday
Abstract
Together with a further improvement of the synthesis of (cyclopentadienyl)trioxorhenium(VII), CpReO3, its reaction chemistry and catalytic activity is also revisited in greater detail. However, in spite of the high catalytic activity of the homologous methyltrioxorhenium(VII) (MTO) and the related CpMo(O2)X, (X = R, Hal, etc.) it is seen that CpReO3 suffers greatly from the lability of the Cp-Re bond under oxidative conditions and in the presence of electron donor ligands. (Cyclopentadienyl)trioxorhenium(VII) although accessible very conveniently, neither matches the rich reaction chemistry of its pentamethylcyclopentadienyl derivative, Cp*ReO3 nor the catalytic versatility of MTO.
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