Zeitschrift für anorganische und allgemeine Chemie

Volume 634, Issue 8 pp. 1403-1408

Article

Adducts of Cyclodiphosph(V)azenes: Synthesis and Structure^†

Christopher Hubrich,

Christopher Hubrich

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

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Dirk Michalik,

Dirk Michalik

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

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Axel Schulz Prof. Dr.,

Corresponding Author

Axel Schulz Prof. Dr.

[email protected]

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

Universität Rostock, Institut für Chemie, Abteilung Anorganische Chemie and Leibniz-Institut für Katalyse e.V. an der Universität, Albert-Einstein-Straße 3a or 29a, D-18059 Rostock / Germany, Fax: (++49 (0)381/498-6382)Search for more papers by this author

Alexander Villinger,

Alexander Villinger

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

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Christopher Hubrich,

Christopher Hubrich

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

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Dirk Michalik,

Dirk Michalik

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

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Axel Schulz Prof. Dr.,

Corresponding Author

Axel Schulz Prof. Dr.

[email protected]

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

Alexander Villinger,

Alexander Villinger

Rostock, Institut für Chemie, Abteilung Anorganische Chemie der Universität

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First published: 26 May 2008

https://doi.org/10.1002/zaac.200800106

Citations: 12

^†

Dedicated to Professor Heinrich Nöth on the Occasion of his 80^th Birthday

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Abstract

The reaction of Ph₂PCl and PhPCl₂ with bis(trimethylsilyl)sulfur diimide in the presence of GaCl₃ and AlCl₃ yields diadducts of the corresponding cyclodiphosph(V)azene: [Ph₂PN]₂·(GaCl₃)₂ (1), [Ph₂PN]₂·(AlCl₃)₂ (2), and [Ph(Cl)PN]₂·(AlCl₃)₂ (3). This reaction is triggered by Lewis acids, which catalyse the (CH₃)₃Si-Cl and S₈ elimination. The structures of 1·2 CH₂Cl₂, 2·2 CH₂Cl₂ and 3 were determined by single crystal X-ray studies (1: triclinic, equation image , a = 9.679(2) Å, b = 9.863(2) Å, c = 11.366(2) Å, α = 113.55(3)°; β = 99.59(3)°; γ = 106.67(3)°; V = 902.8(3) Å³, Z = 1; 2: triclinic, , a = 9.639(2) Å, b = 9.804(2) Å, c = 11.321(2) Å, α = 113.71(3)°; β = 99.44(3)°; γ = 106.70(3)°; V = 889.3(3) Å³, Z = 1; 3: orthorhombic, Pbca, a = 14.853(3) Å, b = 9.261(2) Å, c = 16.631(3) Å, V = 2287.7(8) Å³, Z = 4.

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Volume634, Issue8

July 2008

Pages 1403-1408

Adducts of Cyclodiphosph(V)azenes: Synthesis and Structure^†

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Adducts of Cyclodiphosph(V)azenes: Synthesis and Structure^†