Department Chemie und Biochemie der Ludwig-Maximilians-Universität München, Butenandtstr. 5–13, D-81377 München, GermanySearch for more papers by this author

Richard Betz,

Richard Betz

München, Ludwig-Maximilians-Universität, Department Chemie und Biochemie

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Maximilian Pfister,

Maximilian Pfister

München, Ludwig-Maximilians-Universität, Department Chemie und Biochemie

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Moritz M. Reichvilser,

Moritz M. Reichvilser

München, Ludwig-Maximilians-Universität, Department Chemie und Biochemie

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Peter Klüfers Prof. Dr.,

Corresponding Author

Peter Klüfers Prof. Dr.

[email protected]

München, Ludwig-Maximilians-Universität, Department Chemie und Biochemie

Department Chemie und Biochemie der Ludwig-Maximilians-Universität München, Butenandtstr. 5–13, D-81377 München, GermanySearch for more papers by this author

First published: 26 May 2008

https://doi.org/10.1002/zaac.200800097

Citations: 4

^†

Dedicated to Professor Heinrich Nöth on the Occasion of his 80^th Birthday

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Abstract

The symmetric spiro-selenurane derived from ethylene glycol, 1,4,6,9-tetraoxa-5λ⁴-selena-spiro[4.4]nonane, was prepared from selenium tetrachloride and ethylene glycol and its molecular structure was determined by single crystal X-ray diffraction. NBO analyses for the title compound and a related compound were conducted to assess the role of the stereochemical active lone pair on the selenium atom on the structure.

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Volume634, Issue8

July 2008

Pages 1393-1396

1,4,6,9-Tetraoxa-5λ⁴-selena-spiro[4.4]nonane – A Combined Theoretical and Experimental Study^†

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1,4,6,9-Tetraoxa-5λ4-selena-spiro[4.4]nonane – A Combined Theoretical and Experimental Study†

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1,4,6,9-Tetraoxa-5λ⁴-selena-spiro[4.4]nonane – A Combined Theoretical and Experimental Study^†