Synthesis and Crystal Structures of Two New Layered Manganese(II) Diphosphonates: Mn2[{(O3PCH2)2NHR}(H2O)F]·H2O
Lei Meng
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorJing Li
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorCorresponding Author
Zhen-Gang Sun
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Institute of Chemistry for Functionalized Materials, Liaoning Normal University, Dalian / P. R. China, Tel.: +86-411-82156568; fax: +86-411-82156858Search for more papers by this authorXue-fang Zheng
Dalian / P. R. China, Liaoning Key Laboratory of Bio-Organic Chemistry, Dalian University
Search for more papers by this authorDa-Peng Dong
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorHui Chen
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorYan-Yu Zhu
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorYan Zhao
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorJing Zhang
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorLei Meng
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorJing Li
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorCorresponding Author
Zhen-Gang Sun
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Institute of Chemistry for Functionalized Materials, Liaoning Normal University, Dalian / P. R. China, Tel.: +86-411-82156568; fax: +86-411-82156858Search for more papers by this authorXue-fang Zheng
Dalian / P. R. China, Liaoning Key Laboratory of Bio-Organic Chemistry, Dalian University
Search for more papers by this authorDa-Peng Dong
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorHui Chen
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorYan-Yu Zhu
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorYan Zhao
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorJing Zhang
Dalian / P. R. China, Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University
Search for more papers by this authorAbstract
Two manganese phosphonates Mn2[{(O3PCH2)2NHR}(H2O)F]·H2O (R = −C6H11 (1), −CH2C5H4N (2)) have been synthesized by hydrothermal reaction and characterized by single–crystal X–ray diffraction as well as with infrared spectroscopy, elemental analysis and thermogravimetric analysis. The two isomorphous compounds feature layered structures in ab plane, in which the tetramers comprised of two MnO4F2 and two MnO5F polyhedra are cross–linked via phosphonate oxygen atoms to form MnII phosphonate layers. The organic groups of the ligands are orientated toward the interlayer space.
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