A New Supramolecular Assembly Formed by Melamine and Sulfuric Acid
Axel Heine
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Search for more papers by this authorKerstin Gloe
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Search for more papers by this authorThomas Doert
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Search for more papers by this authorCorresponding Author
Karsten Gloe Prof. Dr.
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Fachrichtung Chemie und Lebensmittelchemie, Technische Universität, D-01062 DresdenSearch for more papers by this authorAxel Heine
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Search for more papers by this authorKerstin Gloe
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Search for more papers by this authorThomas Doert
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Search for more papers by this authorCorresponding Author
Karsten Gloe Prof. Dr.
Dresden, Fachrichtung Chemie und Lebensmittelchemie der TU Dresden
Fachrichtung Chemie und Lebensmittelchemie, Technische Universität, D-01062 DresdenSearch for more papers by this authorAbstract
Polymeric melaminium sulfate [(LH2)2(SO4)2]n has been synthesized by reaction of melamine L with sulfuric acid in aqueous solution. The compound was characterized by elemental analysis, 1H NMR, ESI MS and a single crystal X-ray diffraction analysis. The architecture of the assembly formed is based on hydrogen bonded dimers of diprotonated melaminium cations (LH2)2+ which are linked by a hydrogen bonded network with sulfate ions forming 2D sheets. A 3D polymeric structure results from the presence of mutual hydrogen bonds between sulfate ions and melaminium cations in different sheets. Significant π-π stacking is also present between the aromatic cations in this supramolecular arrangement.
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