A Designed Lithiophilic Carbon Channel on Separator to Regulate Lithium Deposition Behavior
Sainan Xu
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorCorresponding Author
Teng Zhao
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
E-mail: [email protected], [email protected]
Search for more papers by this authorYusheng Ye
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorTianyu Yang
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorRui Luo
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorLi Li
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorFeng Wu
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorCorresponding Author
Renjie Chen
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
E-mail: [email protected], [email protected]
Search for more papers by this authorSainan Xu
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorCorresponding Author
Teng Zhao
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
E-mail: [email protected], [email protected]
Search for more papers by this authorYusheng Ye
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorTianyu Yang
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorRui Luo
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorLi Li
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorFeng Wu
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorCorresponding Author
Renjie Chen
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Institute of Advanced Technology, Beijing Institute of Technology, Jinan, Shandong, 250300 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
E-mail: [email protected], [email protected]
Search for more papers by this authorAbstract
Issues with unstable SEI formation and uncontrollable lithium dendrite growth impede the practical use of lithium anode in high-energy batteries. Herein, a lithiophilic carbon channel on separator is designed to regulate lithium deposition behavior. The designed channel is formed by carbon nanosheet with cubic cavity (CNCC) prepared by hard template method. The CNCC with a large specific surface area and good electrolyte wettability can effectively reduce the local current density. Besides, the CNCC coated separator with high Young's modulus can mechanically inhibit the growth of lithium dendrites. Notably, CNCC coating can become lithiophilic during lithium plating/striping process, which is beneficial for homogeneous lithium deposition and low lithium nucleation overpotential. As a result, based on the CNCC coated separator, the symmetric Li|Li cell cycle over 2600h at 6 mA cm−2 for 2 mAh cm−2, while the Li|Cu cell reaches average Coulombic efficiency of 98.5% at 2 mA cm−2 for 2 mAh cm−2.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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| smll202104390-sup-0001-SuppMat.pdf882.7 KB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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