Volume 219, Issue 15 2100725
Research Article

Magnetic Properties of Tetragonal SmFe12−xMox Alloys in Bulk and Melt-Spun Ribbons

Bosco Rodríguez-Crespo

Bosco Rodríguez-Crespo

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

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Andrés Garcia-Franco

Andrés Garcia-Franco

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

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James Janderson Rosero-Romo

James Janderson Rosero-Romo

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

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Cristina Echevarria-Bonet

Cristina Echevarria-Bonet

Department of Physics, University of Oviedo, 33007 Oviedo, Spain

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Jose Maria Porro

Jose Maria Porro

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

IKERBASQUE, Basque Foundation for Science, Plaza Euskadi 5, 48009 Bilbao, Spain

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Paula G. Saiz

Paula G. Saiz

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

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Daniel Salazar

Corresponding Author

Daniel Salazar

BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

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First published: 09 April 2022

Abstract

Currently, electric motors and generators use high-energy permanent magnets based on RE2Fe14B phases (RE: rare earth) with high amounts of RE often including heavy-RE metals (Dy, Tb), the most critical group of the raw materials. REFe12 alloys are seen as potential alternatives to RE2Fe14B because they contain a significantly lower amount of RE metals with similar or better values of remanent magnetization (MR) and high magnetocrystalline anisotropy, which can give rise to a large energy product (BH)max. Herein, the effect of heat treatments on the coercivity and magnetic properties on melt-spun ribbons of SmFe12−xMox (x = 0.5, 1) alloys with wheel speeds of 15 and 35 m s−1 is studied. The maximum coercivity after heat treatments is obtained in as-spun ribbons at a speed of 35 m s−1. For the x = 0.5 ribbons, μ0Hc increases from 0.06 to 0.36 T, while for the x = 1.0 ones μ0Hc is enhanced from 0.02 to 0.34 T. The highest values of saturation magnetization are obtained for the x = 0.5 ribbons (≈145 Am2 kg−1).

Conflict of Interest

The authors declare no conflict of interest.

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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