Sulfonated syndiotactic polystyrene: sorption of ionic liquid in the amorphous phase and of organic guests in the crystalline phase
Agata Dembna
Institute of Chemical Technology and Engineering, Poznan University of Technology (Politechnika Poznańska), Pl. Sklodowskiej-Curie 2, 60-965 Poznan, Poland
Search for more papers by this authorCorresponding Author
Vincenzo Venditto
Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy
Vincenzo Venditto, Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084, Fisciano, Italy.
E-mail: [email protected]
Search for more papers by this authorAlexandra R. Albunia
Borealis Polyolefine GmbH, St.-Peter-Straβe 25, 4021 Linz Austria
Search for more papers by this authorRosa Califano
Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy
Search for more papers by this authorGaetano Guerra
Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy
Search for more papers by this authorAgata Dembna
Institute of Chemical Technology and Engineering, Poznan University of Technology (Politechnika Poznańska), Pl. Sklodowskiej-Curie 2, 60-965 Poznan, Poland
Search for more papers by this authorCorresponding Author
Vincenzo Venditto
Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy
Vincenzo Venditto, Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084, Fisciano, Italy.
E-mail: [email protected]
Search for more papers by this authorAlexandra R. Albunia
Borealis Polyolefine GmbH, St.-Peter-Straβe 25, 4021 Linz Austria
Search for more papers by this authorRosa Califano
Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy
Search for more papers by this authorGaetano Guerra
Dipartimento di Chimica e Biologia, NANO_MATES Research Centre and INSTM Research Unit, Università degli Studi di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy
Search for more papers by this authorAbstract
Fourier Transform Infrared spectroscopy (FTIR) and Wide-Angle X-Ray Diffraction (WAXD) measurements have clearly established the occurrence of a dual sorption ability of sulfonated syndiotactic polystyrene samples, which exhibit the nanoporous δ crystalline phase. In fact, large uptake (up to 20–30 wt%) of ionic liquid (IL; e.g. 1-ethyl-3-methylimidazolium dicyanamide) occurs only in the hydrophilic amorphous sulfonated phases and does not disturb the hydrophobic nanoporous crystalline δ phase. On the other hand, a large uptake of organic guests (e.g. naphthalene) occurs prevailingly in the nanoporous hydrophobic crystalline phase, independently of the presence of the IL in the amorphous phase, eventually leading to the formation of syndiotactic polystyrene co-crystalline phases. The thermal stability of IL can be largely increased by their inclusion in the amorphous phase of sulfonated syndiotactic polystyrene films. Copyright © 2012 John Wiley & Sons, Ltd.
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