Ring Closing Metathesis Using Chiral Template Consisting of Hard and Soft Parts

Hakim S. M. A. Siddiki,

Hakim S. M. A. Siddiki

Graduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan

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Takashi Sugimura,

Corresponding Author

Takashi Sugimura

[email protected]

Graduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan

Graduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan. Fax: (+81) 791 58 0115Search for more papers by this author

Hakim S. M. A. Siddiki,

Hakim S. M. A. Siddiki

Graduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan

Search for more papers by this author

Takashi Sugimura,

Corresponding Author

Takashi Sugimura

[email protected]

Graduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan

Graduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan. Fax: (+81) 791 58 0115Search for more papers by this author

First published: 26 July 2010

https://doi.org/10.1002/masy.200900039

Citations: 2

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Abstract

Summary: Macrocyclic compounds having 18-, 19-, 22-, and 23-membered rings were prepared quantitatively by ring closing metathesis of diene substrates consisting of a rigid o- or m-phthalate group and flexible but geometrically regulated 2,4-pentanediol tethers. From the p-phthalate analogues, the ring closing metathesis and the cyclic dimmer formation were observed to give 24-membered ring (70% yield) and 40-membered ring (65% yield) respectively.

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Volume293, Issue1

Special Issue:Olefin Metathesis

July 2010

Pages 10-14

Ring Closing Metathesis Using Chiral Template Consisting of Hard and Soft Parts

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Ring Closing Metathesis Using Chiral Template Consisting of Hard and Soft Parts

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