Summary: A membrane of a cobalt tetraazaporphyrin polymer complex was prepared with a nanometer thickness and used as an oxygen-facilitated transport membrane. Rapid and reversible oxygen binding to the cobalt tetraazaporphyrin complex with a polymeric imidazole ligand was observed at low temperature. Oxygen transport through the membrane was facilitated and a high (oxygen/nitrogen) permselectivity of 28 was obtained.

Oxygen-facilitated transport through a cobalt tetraazaporphyrin complex-polymer membrane of nanometer thickness.

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Volume26, Issue6

March 18, 2005

Pages 467-470

Reversible Oxygen Binding to the Polymeric Cobalt Tetraazaporphyrin Complex and Oxygen-Facilitated Transport through Its Membrane

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Reversible Oxygen Binding to the Polymeric Cobalt Tetraazaporphyrin Complex and Oxygen-Facilitated Transport through Its Membrane

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