Influence of Hydrogeological and Climatic Conditions on Piston Flow in Karst Aquifers Using Statistical Approach
Corresponding Author
Javad Ashjari
Haley & Aldrich, Inc., Miamisburg, Ohio, USA
Correspondence:
Javad Ashjari ([email protected])
Search for more papers by this authorAlan E. Fryar
Department of Earth and Environmental Sciences, University of Kentucky, Lexington, Kentucky, USA
Search for more papers by this authorBenjamin Tobin
National Cave & Karst Research Institute, New Mexico Institute of Mining and Technology, Carlsbad, New Mexico, USA
Search for more papers by this authorCorresponding Author
Javad Ashjari
Haley & Aldrich, Inc., Miamisburg, Ohio, USA
Correspondence:
Javad Ashjari ([email protected])
Search for more papers by this authorAlan E. Fryar
Department of Earth and Environmental Sciences, University of Kentucky, Lexington, Kentucky, USA
Search for more papers by this authorBenjamin Tobin
National Cave & Karst Research Institute, New Mexico Institute of Mining and Technology, Carlsbad, New Mexico, USA
Search for more papers by this authorFunding: The authors received no specific funding for this work.
ABSTRACT
Piston flow is a term used to describe the phenomenon of the pressure pulse during pipe-full flow in karst conduits. During piston flow, as dilute meteoric recharge displaces water present in the conduits, discharge increases and specific conductance decreases at karstic springs. The aim of this research is to gain a deeper understanding of how piston flow can be identified on a global scale. To achieve this, the study has defined six phases (stable, lag, hydraulic pressure, mobilisation, dilution and recovery) based on the pattern of hydrographs and specific conductivity time series. Data from 69 flood events at 42 different locations worldwide have been collected and analysed. This analysis considered various factors such as lithology, aquifer type, allogenic or autogenic recharge, precipitation amount and intensity, dry period before storm, hydrograph shape and recession coefficient, specific-conductance time series parameters, memory effect, regulation time and typology of hysteresis loop in order to determine if groups could be differentiated using these parameters. The flood events were classified into two main groups: those with piston flow and those without. Furthermore, the cases with piston flow were categorised into five subgroups based on the location of mobilised stored water. The results show that piston flow can be observed in any karst setting, climatic region and hydrological situation, although it is more likely to occur during extended dry periods preceding a storm, periods of high precipitation and intense rainfall. The mobilised stored water is most likely found in the phreatic zone, but could also be present in the soil or epikarst zone. The occurrence of piston flow depends on the storage capacity of the matrix as well as the development of conduit systems that do not significantly weaken the hydraulic function of the matrix. The typology of hysteresis in piston flow is primarily influenced by the presence of pre-event water or a mixture of pre-event and event water, whereas in systems without piston flow, it is mainly affected by event water.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
Filename | Description |
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hyp70090-sup-0001-Figure_S1.pdfPDF document, 1,017.8 KB |
Figure S1. Locations of selected sites. Numbers refer to site codes of Table S1. |
hyp70090-sup-0002-Suplementry_Tables.docxWord 2007 document , 67.4 KB |
Table S1. Site summaries. Table S2. Statistical summary of main parameters of main groups and subgroups (time units are day). |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- Alberto, W. D., D. M. Del Pilar, A. M. Valeria, P. S. Fabiana, H. A. Cecilia, and B. M. de los Angeles. 2001. “Pattern Recognition Techniques for the Evaluation of Spatial and Temporal Variations in Water Quality, a Case Study: Suquia River Basin (Cordoba–Argentina).” Water Research 35: 2881–2894. https://doi.org/10.1016/S0043-1354(00)00592-3.
- Ashjari, J., and E. Raeisi. 2006. “Lithological Control on Water Chemistry in Karst Aquifers of the Zagros Range, Iran.” Cave and Karst Science 33: 111–118.
- Baedke, S. J., and N. C. Krothe. 2001. “Derivation of Effective Hydraulic Parameters of a Karst Aquifer From Discharge Hydrograph Analysis.” Water Resources Research 37: 13–19. https://doi.org/10.1029/2000WR900247.
- Bailly-Comte, V., H. Jourde, A. Roesch, S. Pistre, and C. Batiot-Guilhe. 2008. “Time Series Analyses for Karst/River Interactions Assessment: Case of the Coulazou River (Southern France).” Journal of Hydrology 349: 98–114. https://doi.org/10.1016/j.jhydrol.2007.10.028.
- Bakalowicz, M. 2005. “Karst Groundwater: A Challenge for New Resources.” Hydrogeology Journal 13: 148–160.
- Barberá, J., and B. Andreo. 2011. “Functioning of a Karst Aquifer From S Spain Under Highly Variable Climate Conditions, Deduced From Hydrochemical Records.” Environment and Earth Science 71, no. 2: 585–599. https://doi.org/10.1007/s12665-011-1382-4.
10.1007/s12665?011?1382?4 Google Scholar
- Barbera, J., and B. Andreo. 2015. “Hydrogeological Processes in a Fluviokarstic Area Inferred From the Analysis of Natural Hydrogeochemical Tracers. The Case Study of Eastern Serrania de Ronda (S Spain).” Journal of Hydrology 523: 500–514. https://doi.org/10.1016/j.jhydrol.2015.01.080.
- Batiot, C., C. Emblanch, and B. Blavoux. 2003. “Carbone Organique Total (Cot) Et Magnésium (Mg2+): Deux Traceur Complémentaires Du Temps De Séjours Dans L'aquifére Karstique.” Comptes Rendus Geoscience 335: 205–214.
- Berglund, J. L., L. Toran, and E. K. Herman. 2019. “Deducing Flow Path Mixing by Storm-Induced Bulk Chemistry and REE Variations in Two Karst Springs: With Trends Like These Who Needs Anomalies?” Journal of Hydrology 571: 349–364. https://doi.org/10.1016/j.jhydrol.2019.01.050.
- Bicalho, C., G. Batiot, J. Seidel, S. Van Exter, and H. Jourde. 2012. “Geochemical Evidence of Water Source Characterization and Hydrodynamic Responses in a Karst Aquifer.” Journal of Hydrology 450: 206–218. https://doi.org/10.1016/j.jhydrol.2012.04.059.
- Birk, S., and S. Hergarten. 2010. “Early Recession Behaviour of Spring Hydrographs.” Journal of Hydrology 387, no. 1–2: 24–32. https://doi.org/10.1016/j.jhydrol.2010.03.026.
- Bonacci, O. 1993. “Karst Springs Hydrographs as Indicators of Karst Aquifers.” Hydrological Sciences Journal 38, no. 1: 51–62.
- Box, G. E. P., G. M. Jenkins, G. C. Reinsel, and G. M. Ljung. 2016. Time Series Analysis: Forecasting and Control. Journal of the American Statical Association, 68, no. 342: 493–494. https://doi.org/10.2307/2284112.
- Butturini, A., M. Alvarez, S. Bernal, E. Vazquez, and F. Sabater. 2008. “Diversity and Temporal Sequences of Forms of DOC and NO3-Discharge Responses in an Intermittent Stream: Predictable or Random Succession?” Journal of Geophysical Research – Biogeosciences 113, no. G3: 2008JG000721. https://doi.org/10.1029/2008JG000721.
10.1029/2008JG000721 Google Scholar
- Chang, Y., A. Hartmann, L. Liu, G. Jiang, and J. Wu. 2021. “Identifying More Realistic Model Structures by Electrical Conductivity Observations of the Karst Spring.” Water Resources Research 57: e2020WR028587. https://doi.org/10.1029/2020WR028587.
- Chang, Y., J. Wu, G. Jiang, L. Liu, T. Reimann, and M. Sauter. 2019. “Modeling Spring Discharge and Solute Transport in Conduits by Coupling CFPv2 to an Epikarst Reservoir for a Karst Aquifer.” Journal of Hydrology 569: 587–599. https://doi.org/10.1016/j.jhydrol.2018.11.075.
- Covington, M., C. M. Wicks, and M. O. Saar. 2009. “A Dimensionless Number Describing the Effects of Recharge and Geometry on Discharge From Simple Karstic Aquifers.” Water Resources Research 45: W11410. https://doi.org/10.1029/2009WR008004.
- Covington, M. D., A. J. Luhmann, C. M. Wicks, and M. O. Saar. 2012. “Process Length Scales and Longitudinal Damping in Karst Conduits.” Journal of Geophysical Research 117: F01025. https://doi.org/10.1029/2011JF002212.
- Desmarais, K., and S. Rojstaczer. 2002. “Inferring Source Waters From Measurements of Carbonate Spring Response to Storms.” Journal of Hydrology 260, no. 1–4: 118–134. https://doi.org/10.1016/S0022-1694(01)00607-2.
- Duran, L., N. Massei, N. Lecoq, M. Fournier, and D. Labat. 2020. “Analyzing Multi-Scale Hydrodynamic Processes in Karst With a Coupled Conceptual Modeling and Signal Decomposition Approach.” Journal of Hydrology 583: 124625. https://doi.org/10.1016/j.jhydrol.2020.124625.
- Duvert, C., H. Jourde, M. Raiber, and M. E. Cox. 2015. “Correlation and Spectral Analyses to Assess the Response of a Shallow Aquifer to Low and High Frequency Rainfall Fluctuations.” Journal of Hydrology 527: 894–907. https://doi.org/10.1016/j.jhydrol.2015.05.054.
- Duy, N. L., T. V. K. Nguyen, D. V. Nguyen, et al. 2021. “Groundwater Dynamics in the Vietnamese Mekong Delta: Trends, Memory Effects, and Response Times.” Journal of Hydrology: Regional Studies 33: 100746. https://doi.org/10.1016/j.ejrh.2020.100746.
- Evans, C., and T. D. Davies. 1998. “Causes of Concentration/Discharge Hysteresis and Its Potential as a Tool for Analysis of Episode Hydrochemistry.” Water Resources Research 34, no. 1: 129–137. https://doi.org/10.1029/97WR01881.
- Fiorillo, F. 2009. “Spring Hydrographs as Indicators of Droughts in a Karst Environment.” Journal of Hydrology 373, no. 3–4: 290–301. https://doi.org/10.1016/j.jhydrol.2009.04.034.
- Fleury, P., V. Plagnes, and M. Bakalowicz. 2007. “Modelling of the Functioning of Karst Aquifers With a Reservoir Model: Application to Fontaine de Vaucluse (South of France).” Journal of Hydrology 345: 38–49. https://doi.org/10.1016/j.jhydrol.2007.07.014.
- Ford, D. C., and P. W. Williams. 2007. Karst Hydrogeology and Geomorphology. John Wiley. https://doi.org/10.1002/9781118684986.
10.1002/9781118684986 Google Scholar
- Gerst, J., B. Schwartz, S. Hyde, and M. Schreiber. 2008. “The Role of Epikarst in Controlling Water Quality.” Geological Society of America Abstracts With Programs 40, no. 6: 380.
- Gil Márquez, J., B. Andreo, and M. Mudarra. 2019. “Combining Hydrodynamics, Hydrochemistry, and Environmental Isotopes to Understand the Hydrogeological Functioning of Evaporite-Karst Springs. An Example From Southern Spain.” Journal of Hydrology 576: 299–314. https://doi.org/10.1016/j.jhydrol.2019.06.055.
- Goldscheider, N., and D. Drew. 2007. Methods in Karst Hydrogeology: IAH: International Contributions to Hydrogeology. Vol. 26. 1st ed. CRC Press. https://doi.org/10.1201/9781482266023.
- Grasso, D. A., and P. Y. Jeannin. 1998. “ Statistical Approach to the Impact of Climatic Variations on Karst Spring Chemical Response P.” In Modelling in Karst Systems, edited by Y. Jeannin and M. Sauter, 59–74. P. Lang.
- Grasso, D. A., P. Y. Jeannin, and F. Zwahlen. 2003. “A Deterministic Approach to the Coupled Analysis of Karst Springs' Hydrographs and Chemographs.” Journal of Hydrology 271: 65–76. https://doi.org/10.1016/S0022-1694(02)00321-9.
- Guo, F., G. H. Jiang, and F. Liu. 2021. “Biological Sulfate Reduction in an Epigene Karst Aquifer and Its Impact on Cave Environment.” Journal of Hydrology 602: 126804. https://doi.org/10.1016/j.jhydrol.2021.126804.
- Hartmann, A., and A. Baker. 2017. “Modelling Karst Vadose Zone Hydrology and Its Relevance for Paleoclimate Reconstruction.” Earth-Science Reviews 172: 178–192. https://doi.org/10.1016/j.earscirev.2017.08.001.
- Hartmann, A., J. A. Barberá, and B. Andreo. 2017. “On the Value of Water Quality Data and Informative Flow States in Karst Modelling.” Hydrology and Earth System Sciences 21: 5971–5985. https://doi.org/10.5194/hess-21-5971-2017.
- Jacob, T., J. Chery, R. Bayer, et al. 2009. “Time-Lapse Surface to Depth Gravity Measurements on a Karst System Reveal the Dominant Role of the Epikarst as a Water Storage Entity.” Geophysical Journal International 177, no. 2: 347–360. https://doi.org/10.1111/j.1365-246X.2009.04118.x.
- Jeannin, P. Y., and M. Sauter. 1998. “Analysis of Karst Hydrodynamic Behaviour Using Global Approaches: A Review.” Bulletin d'Hydrogéologie 16: 31–48.
- Jódar, J., A. González-Ramón, S. Martos-Rosillo, et al. 2020. “Snowmelt as a Determinant Factor in the Hydrogeological Behaviour of High Mountain Karst Aquifers: The Garcés Karst System, Central Pyrenees (Spain).” Science of the Total Environment 748: 141363. https://doi.org/10.1016/j.scitotenv.2020.141363.
- Jukić, D., V. Denić-Jukić, and A. Kadić. 2022. “Temporal and Spatial Characterization of Sediment Transport Through a Karst Aquifer by Means of Time Series Analysis.” Journal of Hydrology 609: 127753. https://doi.org/10.1016/j.jhydrol.2022.127753.
- Kiraly, L. 2003. “Karstification and Groundwater Flow.” Speleogenes Evol Karst Aquifer 1: 1–26.
- Kovačič, G. 2010. “Hydrogeological Study of Themalenščica Karst Spring (SW Slovenia) by Means of a Time Series Analysis.” Acta Carsologica 39, no. 2: 201–215.
- Kovács, A. 2003. “Geometry and Hydraulic Parameters of Karst Aquifers: A Hydrodynamic Modeling Approach.” Ph.D. thesis, Université de Neuchâtel, Switzerland.
- Kovács, A., and P. Perrochet. 2008. “A Quantitative Approach to Spring Hydrograph Decomposition.” Journal of Hydrology 352: 16–29. https://doi.org/10.1016/j.jhydrol.2007.12.009.
- Kovács, A., P. Perrochet, L. Király, and P. Y. Jeannin. 2005. “A Quantitative Method for the Characterization of Karst Aquifers Based on Spring Hydrograph Analysis.” Journal of Hydrology 303: 152–164. https://doi.org/10.1016/j.jhydrol.2004.08.023.
- Lam-Hoai, T., and C. Rougier. 2001. “Zooplankton Assemblages and Biomass During a 4-Period Survey in a Northern Mediterranean Coastal Lagoon.” Water Research 35: 271–283.
- Larocque, M., A. Mangin, M. Razack, and O. Banton. 1998. “Contribution of Correlation and Spectral Analyses to the Regional Study of a Large Karst Aquifer (Charente, France).” Journal of Hydrology 205: 217–231. https://doi.org/10.1016/S0022-1694(97)00155-8.
- Le Mesnil, M., J. B. Charlier, R. Moussa, and Y. Caballero. 2022. “Investigating Flood Processes in Karst Catchments by Combining Concentration-Discharge Relationship Analysis and Lateral Flow Simulation.” Journal of Hydrology 605: 127358. https://doi.org/10.1016/j.jhydrol.2021.127358.
- Liu, Z., Q. Li, H. Sun, and J. Wang. 2007. “Seasonal, Diurnal and Storm-Scale Hydrochemical Variations of Typical Epikarst Springs in Subtropical Karst Areas of SW China: Soil CO2 and Dilution Effects.” Journal of Hydrology 337, no. 1–2: 207–223. https://doi.org/10.1016/j.jhydrol.2007.01.034.
- Maillet, E. 1905. Essais D'hydraulique Souterraine Et Fluviale, 278. Kessinger Publishing.
- Mangin, A. 1975. “Contribution À L'étude Hydrodynamique Des Aquifères Karstiques. 3eme Partie.” Annales de Spéléologie 30, no. 1: 21–124.
- Mangin, A. 1984. “Pour Une Meilleure Connaissance Des Systémes Hydrologiques À Partir Des Analyses Correlatoire Et Spectrale.” Journal of Hydrology 67: 25–43.
- Mangin, A. 1994. “ Karst Hydrogeology.” In Groundwater Ecology, edited by J. Gibert, D. L. Danielopol, and J. A. Stanford, 43–67. Academic Press Limited.
10.1016/B978-0-08-050762-0.50009-7 Google Scholar
- Marsaud, B. 1997. “Structure Et Fonctionnement De La Zone Noyée Des Karsts À Partir Des Résultats Expérimentaux.” Ph.D. thesis, Université Paris XI Orsay, France.
- Massei, N., J. P. Dupont, B. J. Mahler, et al. 2006. “Investigating Transport Properties and Turbidity Dynamics of a Karst Aquifer Using Correlation, Spectral, and Wavelet Analyses.” Journal of Hydrology 329, no. 1–2: 244–257. https://doi.org/10.1016/j.jhydrol.2006.02.021.
- Massei, N., B. J. Mahler, M. Bakalowicz, M. Fournier, and J. P. Dupont. 2007. “Quantitative Interpretation of Specific Conductance Frequency Distributions in Karst.” Ground Water 45, no. 3: 288–293. https://doi.org/10.1111/j.1745-6584.2006.00291.x.
- Mitrofan, H., C. Marin, and L. Povară. 2015. “Possible Conduit-Matrix Water Exchange Signatures Outlined at a Karst Spring.” Groundwater 53, no. S1: 113–122. https://doi.org/10.1111/gwat.12292.
- Mudarra, M., and B. Andreo. 2011. “Relative Importance of the Saturated and the Unsaturated Zones in the Hydrogeological Functioning of Karst Aquifers: The Case of Alta Cadena (Southern Spain).” Journal of Hydrology 397: 263–280. https://doi.org/10.1016/j.jhydrol.2010.12.005.
- Mudarra, M., B. Andreo, J. A. Barberá, and J. Mudry. 2014. “Hydrochemical Dynamics of TOC and NO3—Contents as Natural Tracers of Infiltration in Karst Aquifers.” Environment and Earth Science 71, no. 2: 507–523. https://doi.org/10.1007/s12665-013-2593-7.
- Nannoni, A., and L. Piccini. 2022. “Mixed Recharge and Epikarst Role in a Complex Metamorphic Karst Aquifer: The Pollaccia System, Apuan Alps (Tuscany, Italy).” Hydrology 9, no. 5: 83. https://doi.org/10.3390/hydrology9050083.
- Newson, M. D., E. T. Shuster, and W. B. White. 1972. “Comment on “Seasonal Fluctuations in the Chemistry of Limestone Springs” by Evan T. Shuster and William B. White.” Journal of Hydrology 16, no. 1: 49–51. https://doi.org/10.1016/0022-1694(72)90174-6.
10.1016/0022-1694(72)90173-4 Google Scholar
- Olarinoye, T., T. Gleeson, and A. Hartmann. 2022. “Karst Spring Recession and Classification: Efficient, Automated Methods for Both Fast- and Slow-Flow Components.” Hydrology and Earth System Sciences 26: 5431–5447. https://doi.org/10.5194/hess-26-5431-2022.
- Padilla, A., and A. Pulido-Bosch. 1995. “Study of Hydrographs of Karstic Aquifers by Means of Correlation and Cross-Spectral Analysis.” Journal of Hydrology 168: 73–89. https://doi.org/10.1016/0022-1694(94)02648-U.
- Padilla, A., A. Pulido-Bosch, and A. Mangin. 1994. “Relative Importance of Baseflow and Quickflow From Hydrographs of Karst Spring.” Ground Water 32, no. 2: 267–277. https://doi.org/10.1111/j.1745-6584.1994.tb00641.x.
- Paiva, I., and L. Cunha. 2020. “Characterization of the Hydrodynamic Functioning of the Degracias-Sicó Karst Aquifer Portugal.” Hydrogeology Journal 28, no. 7: 2613–2629. https://doi.org/10.1007/s10040-020-02201-2.
- Panagopoulos, G., and N. Lambrakis. 2006. “The Contribution of Time Series Analysis to the Study of the Hydrodynamic Characteristics of the Karst Systems: Application on Two Typical Karst Aquifers of Greece (Trifilia, Almyros Crete).” Journal of Hydrology 329: 368–376. https://doi.org/10.1016/j.jhydrol.2006.02.023.
- Perrin, J., P. Y. Jeannin, and F. Zwahlen. 2003. “Epikarst Storage in a Karst Aquifer:A Conceptual Model Based on Isotopic Data, Milandre Test Site, Switzerland.” Journal of Hydrology 279, no. 1–4: 106–124. https://doi.org/10.1016/S0022-1694(03)00171-9.
- Raeisi, E., C. Groves, and J. Meiman. 2007. “Effects of Partial and Full Pipe Flow on Hydro-Chemographs of Logsdon River, Mammoth Cave Kentucky USA.” Journal of Hydrology 337, no. 1–2: 1–10. https://doi.org/10.1016/j.jhydrol.2006.11.015.
- Raeisi, E., and G. Karami. 1997. “Hydrochemographs of Berghan Karst Spring as Indicators of Aquifer Characteristics.” Journal of Cave and Karst Studies 59, no. 3: 112–118.
- Ravbar, N., I. Engelhardt, and N. Goldscheider. 2011. “Anomalous Behaviour of Specific Electrical Conductivity at a Karst Spring Induced by Variable Catchment Boundaries: The Case of the Podstenjšek Spring, Slovenia.” Hydrological Processes 25: 2130–2140.
- Ravichandran, S. 1987. “Water Quality Studies on Buckingham Canal (Madras, India) a Discriminant Analysis.” Hydrobiologia 154: 121–126.
- Rose, S. 2003. “Comparative Solute–Discharge Hysteresis Analysis for an Urbanized and a “Control Basin” in the Georgia (USA) Piedmont.” Journal of Hydrology 284, no. 1–4: 45–56. https://doi.org/10.1016/j.jhydrol.2003.07.001.
- Ryan, M., and J. Meiman. 1996. “An Examination of Short-Term Variations in Water Quality at a Karst Spring in Kentucky.” Ground Water 34, no. 1: 23–30. https://doi.org/10.1111/j.1745-6584.1996.tb01861.x.
- Schuler, P., L. Duran, P. Johnston, and L. Gill. 2020. “Quantifying and Numerically Representing Recharge and Flow Components in a Karstified Carbonate Aquifer.” Water Resources Research 56: e2020WR027717. https://doi.org/10.1029/2020wr027717.
- Schwartz, B. F., S. Schwinning, B. Gerard, K. R. Kukowski, C. L. Stinson, and H. C. Dammeyer. 2013. “Using Hydrogeochemical and Ecohydrologic Responses to Understand Epikarst Process in Semi-Arid Systems, Edwards Plateau, Texas, USA.” Acta Carsologica 42, no. 2–3: 315–325.
- Shuster, E. T., and W. B. White. 1971. “Seasonal Fluctuations in the Chemistry of Limestone Springs: A Possible Means of Characterizing Carbonate Aquifers.” Journal of Hydrology 14: 93–128. https://doi.org/10.1016/0022-1694(71)90001-1.
10.1016/0022-1694(71)90001-1 Google Scholar
- Taylor, C. J., and E. A. Greene. 2008. “ Hydrogeologic Characterization and Methods Used in the Investigation of Karst Hydrology.” In Field Techniques for Estimating Water Fluxes Between Surface Water and Ground Water, 75–114. US Geol Surv, Techniques Methods 4-D2.
- Ternan, J. L. 1972. “Comments on the Use of a Calcium Hardness Variability Index in the Study of Carbonate Aquifers: With Reference to the Central Pennines, England.” Journal of Hydrology 16: 317–321. https://doi.org/10.1016/0022-1694(72)90136-9.
10.1016/0022-1694(72)90136-9 Google Scholar
- Tobin, B. W., J. S. Polk, S. M. Arpin, A. Shelley, and C. Taylor. 2021. “A Conceptual Model of Epikarst Processes Across Sites, Seasons, and Storm Events.” Journal of Hydrology 596: 125692. https://doi.org/10.1016/j.jhydrol.2020.125692.
- Toran, L., and C. E. Reisch. 2013. “Using Stormwater Hysteresis to Characterize Karst Spring Discharge.” Ground Water 51: 1745–6584. https://doi.org/10.1111/j.1745-6584.2012.00984.x.
10.1111/j.1745-6584.2012.00984.x Google Scholar
- Torresan, F., P. Fabbri, L. Piccinini, N. Dalla Libera, M. Pola, and D. Zampieri. 2020. “Defining the Hydrogeological Behavior of Karst Springs Through an Integrated Analysis: A Case Study in the Berici Mountains Area (Vicenza, NE Italy).” Hydrogeology Journal 28: 1229–1247. https://doi.org/10.1007/s10040-020-02122-0.
- Valdes, D., J. P. Dupont, N. Massei, B. Laignel, and J. Rodet. 2006. “Investigation of Karst Hydrodynamics and Organization Using Autocorrelations and T–ΔC Curves.” Journal of Hydrology 329: 432–443. https://doi.org/10.1016/j.jhydrol.2006.02.030.
- Vaughan, M. C. H., W. B. Bowden, J. B. Shanley, et al. 2017. “High Frequency Dissolved Organic Carbon and Nitrate Measurements Reveal Differences in Storm Hysteresis and Loading in Relation to Land Cover and Seasonality.” Water Resources Research 53, no. 7: 5345–5363. https://doi.org/10.1002/2017WR020491.
- White, W. B. 2002. “Karst Hydrology: Recent Developments and Open Questions.” Engineering Geology 65: 85–105. https://doi.org/10.1016/S0013-7952(01)00116-8.
- Wicks, C., and J. Engeln. 1997. “Geochemical Evolution of a Karst Stream in Devils Icebox Cave, Missouri, USA.” Journal of Hydrology 198, no. 1–4: 30–41. https://doi.org/10.1016/S0022-1694(96)03328-8.
- Williams, P. W. 2008. “The Role of the Epikarst in Karst and Cave Hydrogeology: A Review.” International Journal of Speleology 37: 1–10. https://digitalcommons.usf.edu/ijs/vol37/iss1/1.
- Winston, W. E., and R. E. Criss. 2004. “Dynamic Hydrologic and Geochemical Response in a Perennial Karst Spring.” Water Resources Research 40: W05106. https://doi.org/10.1029/2004wr003054.
- Worthington, S. R. H., G. J. Davies, and J. F. Quinlan. 1992. “ Geochemistry of Springs in Temperate Carbonate Aquifers: Recharge Type Explain Most of the Variation.” In Proceedings of 5th Conference on Limestone Hydrology and Fissured Media, edited by P. Chauve and F. Zwahlen, 341–347. Universities of Neuchatel and Besançon.
- Yang, R., Z. Liu, C. Zeng, and M. Zhao. 2012. “Response of Epikarst Hydrochemical Changes to Soil CO2 and Weather Conditions at Chenqi, Puding, SW China.” Journal of Hydrology 468: 151–158. https://doi.org/10.1016/j.jhydrol.2012.08.029.
- Zhang, R., X. Chen, Z. Zhang, and C. Soulsby. 2020. “Using Hysteretic Behaviour and Hydrograph Classification to Identify Hydrological Function Across the “Hillslope–Depression–Stream” Continuum in a Karst Catchment.” Hydrological Processes 34, no. 16: 3464–3480. https://doi.org/10.1002/hyp.13793.