REVIEW PAPER
Metal-organic frameworks and their derivatives as anode material in lithium-ion batteries: Recent advances towards novel configurations
Rajnish Kaur,
Varun A. Chhabra,
Vikas Chaudhary,
Kumar Vikrant,
Surya Kant Tripathi,
Yanjie Su,
Parveen Kumar,
Ki-Hyun Kim,
Akash Deep,
Rajnish Kaur
Department of Physics, Panjab University (PU), Chandigarh, India
Search for more papers by this authorVarun A. Chhabra
Chitkara University Institute of Engineering and Technology, Chitkara University, Punjab, India
Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea
Search for more papers by this authorVikas Chaudhary
Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Search for more papers by this authorKumar Vikrant
Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea
Search for more papers by this authorSurya Kant Tripathi
Department of Physics, Panjab University (PU), Chandigarh, India
Search for more papers by this authorYanjie Su
Department of Micro/Nano Electronics, Key Laboratory for Thin Film and Microfabrication (Ministry of Education), Shanghai Jiao Tong University, Shanghai, P.R. China
Search for more papers by this authorParveen Kumar
Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Search for more papers by this authorCorresponding Author
Ki-Hyun Kim
Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea
Correspondence
Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea.
Email: [email protected]
Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Akash Deep
Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Correspondence
Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea.
Email: [email protected]
Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India.
Email: [email protected]
Search for more papers by this authorRajnish Kaur,
Varun A. Chhabra,
Vikas Chaudhary,
Kumar Vikrant,
Surya Kant Tripathi,
Yanjie Su,
Parveen Kumar,
Ki-Hyun Kim,
Akash Deep,
Rajnish Kaur
Department of Physics, Panjab University (PU), Chandigarh, India
Search for more papers by this authorVarun A. Chhabra
Chitkara University Institute of Engineering and Technology, Chitkara University, Punjab, India
Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea
Search for more papers by this authorVikas Chaudhary
Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Search for more papers by this authorKumar Vikrant
Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea
Search for more papers by this authorSurya Kant Tripathi
Department of Physics, Panjab University (PU), Chandigarh, India
Search for more papers by this authorYanjie Su
Department of Micro/Nano Electronics, Key Laboratory for Thin Film and Microfabrication (Ministry of Education), Shanghai Jiao Tong University, Shanghai, P.R. China
Search for more papers by this authorParveen Kumar
Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Search for more papers by this authorCorresponding Author
Ki-Hyun Kim
Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea
Correspondence
Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea.
Email: [email protected]
Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Akash Deep
Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India
Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Correspondence
Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea.
Email: [email protected]
Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India.
Email: [email protected]
Search for more papers by this authorRajnish Kaur, Varun A. Chhabra, Vikas Chaudhary are first authors and contributed equally to this work.
Funding information: National Research Foundation of Korea (NRF) funded by the Ministry of Science and ITC (MSIT) of Korean government, Grant/Award Number: 2021R1A3B1068304; UGC, India, Grant/Award Number: PH/20-21/0192
Summary
Lithium-ion batteries (LIBs) have drawn extensive research interests due to their noticeably enhanced gravimetric energy density relative to other chemical batteries. The potential utility of metal-organic frameworks (MOFs) and their derivatives has recently been recognized as highly effective anode components for LIBs because they can be tuned to select specific metal sites and/or to adjust pore sizes. In this work, their electrochemical performance as anodic materials is carefully evaluated with respect to lithium-ions storage capacity, energy/power, stability, and flexibility. Furthermore, through the coordination of the organic linker and metal center, MOFs can benefit from enhanced catalytic activities in the design of advanced LIBs. For future research for next-generation LIBs, scientific focus should be placed on the development of diverse features of MOF-based composites such as core-shell MOFs, mono/bi-metal doped MOFs, dual organic linker-based MOFs, MOFs@MOFs core shell structure, and dual organic ligands-based MOF. As such, MOF-based LIB electrode materials are expected to expand their utility with the improvement in topology and functionality in association with the dimensionality, pore size, and surface area.
Open Research
DATA AVAILABILITY STATEMENT
The data that supports the findings of this study are available in the supplementary material of this article.
Supporting Information
| Filename | Description |
|---|---|
| er8046-sup-0001-Supinfo.docxWord 2007 document , 290 KB | Appendix S1. Supporting Information. Figure S1. A schematic of the synthesis procedure use to prepare the Co3O4/nitrogen doped porous carbon composite from ZIF-67 [1]. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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