Incorporation of pyridinic and graphitic N to Ni@CNTs: As a competent electrocatalyst for hydrogen evolution reaction
Chidinma Judith Oluigbo
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorNabi Ullah
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorCorresponding Author
Meng Xie
School of Pharmacy, Jiangsu University, Zhenjiang, China
Correspondence
Yuanguo Xu, School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Meng Xie, School of Pharmacy, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Search for more papers by this authorChukwuma Christian Okoye
Department of Chemistry, Faculty of Natural Sciences, University of Jos, Jos, Nigeria
Search for more papers by this authorBashir Adegbemiga Yusuf
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorWaleed Yaseen
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorJagadeeh Kumar Alagarasan
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorKanagaraj Rajalakshmi
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorCorresponding Author
Yuanguo Xu
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Correspondence
Yuanguo Xu, School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Meng Xie, School of Pharmacy, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Search for more papers by this authorJimin Xie
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorChidinma Judith Oluigbo
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorNabi Ullah
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorCorresponding Author
Meng Xie
School of Pharmacy, Jiangsu University, Zhenjiang, China
Correspondence
Yuanguo Xu, School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Meng Xie, School of Pharmacy, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Search for more papers by this authorChukwuma Christian Okoye
Department of Chemistry, Faculty of Natural Sciences, University of Jos, Jos, Nigeria
Search for more papers by this authorBashir Adegbemiga Yusuf
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorWaleed Yaseen
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorJagadeeh Kumar Alagarasan
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorKanagaraj Rajalakshmi
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorCorresponding Author
Yuanguo Xu
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Correspondence
Yuanguo Xu, School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Meng Xie, School of Pharmacy, Jiangsu University, Zhenjiang 212013, China.
Email: [email protected]
Search for more papers by this authorJimin Xie
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, China
Search for more papers by this authorFunding information: National Natural Science Foundation of China, Grant/Award Number: 21676129; The Science and Technology Foundation of Zhenjiang, Grant/Award Numbers: GY2016021, GY2017001, YE201709
Summary
Cheap production of hydrogen (H2) from eco-friendly routes is preeminent for solving future energy challenges. This study explores the hydrogen evolution reaction (HER) activity of nickel (Ni) nanoparticles and nitrogen doped carbon nanotubes (NiNCNTs), which are fabricated by a cheap and one-step pyrolysis method. The most active catalyst synthesized at 800°C exhibits an overpotential of 0.244 V to reach a current density of 10 mA cm−2, Tafel slope of 93.3 mV dec−1 and a satisfactory 10 hours stability. Low resistance and large ECSA value of the sample also favor the competent response for HER in alkaline media. The robust HER activity of the catalyst is as a result of the nickel nanoparticles which are the active spots of reaction; while the presence of well-developed nitrogen containing carbon nanotubes with large content of pyridinic and graphitic nitrogen may provide high-electron density and feasible routes for its transportation to deliver an outstanding HER performance.
Supporting Information
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