Enhancing Supercapacitor Performance of NiCoMn-Layered Double Hydroxide with Ag–Citrate/Polyaniline Nanocomposites
Ammar Makda
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorCorresponding Author
Mohsin Ali Marwat
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586 Saudi Arabia
Search for more papers by this authorMuhammad Hamza Mahmood
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorAbdullah Naeem
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorSyed Muhammad Abdullah
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorMuhammad Humayun
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586 Saudi Arabia
Search for more papers by this authorMuhammad Ramzan Abdul Karim
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorMohamed Bououdina
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586 Saudi Arabia
Search for more papers by this authorMuhammad Zubair Khan
Department of Materials Science & Engineering, Pak-Austria Fachhochschule: Institute of Applied Sciences and Technology, Mang, Haripur, KPK, 22621 Pakistan
Search for more papers by this authorMuhammad Bilal Hanif
Department of Inorganic Chemistry, Comenius University Bratislava, Ilkovicova 6, 842 15 Bratislava, Slovakia
Search for more papers by this authorAmmar Makda
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorCorresponding Author
Mohsin Ali Marwat
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586 Saudi Arabia
Search for more papers by this authorMuhammad Hamza Mahmood
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorAbdullah Naeem
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorSyed Muhammad Abdullah
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorMuhammad Humayun
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586 Saudi Arabia
Search for more papers by this authorMuhammad Ramzan Abdul Karim
Faculty of Materials and Chemical Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Sciences and Technology, Topi, 23640 Pakistan
Search for more papers by this authorMohamed Bououdina
Energy, Water, and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586 Saudi Arabia
Search for more papers by this authorMuhammad Zubair Khan
Department of Materials Science & Engineering, Pak-Austria Fachhochschule: Institute of Applied Sciences and Technology, Mang, Haripur, KPK, 22621 Pakistan
Search for more papers by this authorMuhammad Bilal Hanif
Department of Inorganic Chemistry, Comenius University Bratislava, Ilkovicova 6, 842 15 Bratislava, Slovakia
Search for more papers by this authorAbstract
Layered double hydroxide (LDH) has a layered structure, which makes it a strong candidate for supercapacitors (SC) due to its high surface area. However, they suffer from low conductivity due to insufficient charge transfer across their layers. This research aims to overcome this obstacle by introducing conductive channels among the layers by the addition of Ag–citrate and polyaniline (PANI). Consequently, five electrodes (S1–5) were made from NiCoMn LDH (referred to as LDH henceforth) and 2:1 Ag–citrate and PANI composite (Ag/PANI) in different ratios and made into electrodes. Electrochemical analysis revealed successful improvement in the performance of LDH as the fraction of Ag/PANI increased until it equaled Ag/PANI where the highest specific capacitance of 617 F g−1 was obtained, which is 12% greater than the value for solely LDH electrode (550 F g−1). A device was fabricated with the best electrode (S3) and activated carbon electrode, which demonstrated energy densities and power densities of 41 WhKg−1 and 412.5 W Kg−1 and 14 WhKg−1and 8250 W Kg−1 at 0.5 and 10 A g−1 current densities, respectively. It also exhibited a capacitive retention of about 75% at 3000 galvanostatic charge–discharge cycles. These results encourage the use in of NiCoMn LDH, in a 1:1 ratio with Ag/PANI in SCs due to its remarkable performance.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1 S. S. Shah, M. A. Aziz, M. A. Marzooqi, A. Z. Khan, Z. H. Yamani, J. Power Sources 2024, 602, 234334.
- 2 S. M. Abdullah, M. A. Marwat, K. M. Adam, Z. U. Din, M. Humayun, M. R. Abdul Karim, E. Ghazanfar, M. Bououdina, U. Hamayun, M. S. Youssef, H. T. Ali, RSC Adv. 2024, 14, 14438.
- 3 S. Panda, K. Deshmukh, S. K. Khadheer Pasha, J. Theerthagiri, S. Manickam, M. Y. Choi, Coord. Chem. Rev. 2022, 462, 214518.
- 4 K. M. Adam, M. A. Marwat, M. F. Khan, M. Humayun, S. S. Shah, Z. U. Din, M. R. A. Karim, M. Bououdina, S. Abdullah, E. Ghazanfar, J. Energy Storage 2024, 81, 110448.
- 5 A. Muzaffar, M. B. Ahamed, C. M. Hussain, Renewable Sustainable Energy Rev. 2024, 195, 114324.
- 6 M. A. Marwat, H. Zhang, M. Humayun, B. Xie, M. Ashtar, M. Bououdina, M. U. Rehman, S. Ishfaq, J. Energy Storage 2024, 79, 110125.
- 7 S. Ali, M. A. Marwat, M. F. Khan, K. M. Adam, Z. U. Din, M. R. A. Karim, S. Khan, J. Alloys Compd. 2023, 956, 170229.
- 8 M. A. Marwat, S. Ishfaq, K. M. Adam, B. Tahir, M. H. Shaikh, M. F. Khan, M. R. Abdul Karim, Z. U. Din, S. Abdullah, E. Ghazanfar, RSC Adv. 2024, 14, 2102.
- 9 M. Nehra, N. Dilbaghi, G. Marrazza, A. Kaushik, R. Abolhassani, Y. K. Mishra, K. H. Kim, S. Kumar, Nano Energy 2020, 76, 104991.
- 10 M.A. Marwat, H. Zhang, M. Humayun, B. Xie, M. Ashtar, M. Bououdina, M.U. Rehman, S. Ishfaq, J. Energy Storage, 2024, 79, 110125
- 11 H. A. Khan, M. Tawalbeh, B. Aljawrneh, W. Abuwatfa, A. Al-Othman, H. Sadeghifar, A. G. Olabi, Energy 2024, 295, 131043.
- 12 Z. U. Din, M. A. Marwat, M. Humayun, H. Zhang, B. Xie, S. U. Khan, M. F. Khan, K. M. Adam, S. Abdullah, E. Ghazanfar, J. Energy Storage 2024, 75, 109706.
- 13 Y. Li, Q. Zhang, Y. Liu, P. Zhang, C. Ren, H. Zhang, H. Cai, G. Ding, Z. Yang, C. Zhang, Nano Energy 2021, 89, 106390.
- 14 J. Hao, B. Wang, H. Xu, J. Du, C. Wu, W. Qin, X. Wu, J. Energy Storage 2024, 86, 111301.
- 15 M. Fawad Khan, M. Ali Marwat, M. Abdullah, S. Shaheen Shah, M. R. Abdul Karim, M. Abdul Aziz, Z. Ud Din, Z. Saad Ali, K. Muhammad Adam, Sep. Purif. Technol. 2023, 310, 123101.
- 16 X. Li, D. Du, Y. Zhang, W. Xing, Q. Xue, Z. Yan, J. Mater. Chem. A 2017, 5, 15460.
- 17 K. Narthana, G. Durai, P. Kuppusami, J. Theerthagiri, S. Sujatha, S. J. Lee, M. Y. Choi, Int. J. Energy Res. 2021, 45, 9983.
- 18 J. Theerthagiri, K. Karuppasamy, C. Justin Raj, G. Maia, M. L. Aruna Kumari, L. John Kennedy, M. K. R. Souza, E. S. F. Cardoso, S. Kheawhom, H.-S. Kim, M. Y. Choi, Coord. Chem. Rev. 2024, 513, 215880.
- 19 J. Wu, W. Raza, P. Wang, A. Hussain, Y. Ding, J. Yu, Y. Wu, J. Zhao, Electrochim. Acta 2022, 418, 140339.
- 20 R. Manzar, M. Saeed, U. Shahzad, J. Y. Al-Humaidi, S. Ur Rehman, R. H. Althomali, M. M. Rahman, Prog. Mater. Sci. 2024, 144, 101286.
- 21 J. Ran, Y. Liu, H. Feng, H. Shi, Q. Ma, J. Ind. Eng. Chem. 2024, 137, 106.
- 22 Y. Zhang, Y. Chen, K. Liang, Y. Zhang, D. Wang, W. Wang, J. Wang, X. Du, N. Mitsuzaki, Z. Chen, J. Energy Storage 2024, 91, 112167.
- 23 Y. Ding, Z. Yan, G. Wang, H. Sang, Z. Xu, W. Li, Small 2024, 20, 2306382.
- 24 H. Chen, E. Bao, H. Sun, X. Ren, X. Han, Y. Wang, Z. Zhang, C. Luo, C. Xu, J. Colloid Interface Sci. 2024, 664, 117.
- 25 S. Shaheen Shah, S. Oladepo, M. Ali Ehsan, W. Iali, A. Alenaizan, M. Nahid Siddiqui, M. Oyama, A. Al-Betar, M. A. Aziz, Chem. Rec. 2024, 24, e202300105.
- 26 H. Torun, S. R. Tokgöz, M. Arslan Çarpan, M. H. Somay, A. Peksöz, J. Energy Storage 2024, 88, 111462.
- 27 E. Shanmugasundaram, V. Ganesan, V. Narayanan, K. Vellaisamy, N. Saleh, S. Thambusamy, Nanoscale Adv. 2024, 6, 1765.
- 28 M. Hussain, A. W. Alrowaily, B. M. Alotaibi, H. A. Alyousef, N. Al-Harbi, A. Dahshan, K. Ahmad, M. J. Khan, A. M. A. Henaish, Int. J. Hydrogen Energy 2024, 71, 422.
- 29 K. Chinnaiah, K. Kannan, N. Palko, M. Grishina, L. Guganathan, K. Gurushankar, Ionics 2024, 30, 1691.
- 30 A. Irshad, S. Zulfiqar, Z. A.Alothman, I. Shakir, M. Farooq Warsi, E. W. Cochran, Fuel 2024, 362, 130705.
- 31 G. A. Naikoo, M. A. S. Tabook, B. A. M. Tabook, M. Bano, I. U. Hassan, R. A. Dar, T. A. Saleh, J. Energy Storage 2024, 85, 111047.
- 32 Y. Zhang, Y. Yao, H. Ye, J. Chen, L. Wan, C. Du, Y. Zhang, M. Xie, J. Energy Storage 2024, 91, 112117.
- 33 T. Li, Y. Hu, J. Zhang, H. Li, K. Fang, J. Wang, Z. Wang, M. Xu, B. Zhao, Nano Energy 2024, 126, 109690.
- 34
R. Sonia, L. Phor, A. Kumar, S. Chahal, J. Energy Storage 2024, 84, 110698.
10.1016/j.est.2024.111012 Google Scholar
- 35 T. Zahra, I. Barsoum, F. F. Alharbi, Z. Ahmad, H. H. Somaily, M. Abdullah, H. Alqurashi, I. A. Weinstein, A. M. A. Henaish, H. M. T. Farid, J. Energy Storage 2024, 87, 111470.
- 36 M. A. Raza, M. I. Yousaf, S. Akram, A. Siddique, M. Ashraf, D. J. Fu, Synth. Met. 2024, 301, 117534.
- 37 S. K. Shinde, S. S. Karade, N. T. N. Truong, S. S. Veer, S. F. Shaikh, A. M. Al-Enizi, A. D. Jagadale, H. M. Yadav, M. S. Tamboli, C. Park, D.-Y. Kim, J. Energy Storage 2024, 78, 109960.
- 38 J. Wang, J. Li, F. Wang, X. Zhang, X. Wu, J. Zhang, S. Niu, L. Chen, Chem. Eng. J. 2024, 488, 150932.
- 39 K. J. Jothi, R. D. Kumar, I. Hasan, S. Balachandran, M. M. Mohideen, T. Preethi, N. Prakash, B.-K. Lee, J. Energy Storage 2024, 75, 109597.
- 40 X. Guan, X. Fan, E. Zhu, J. Zhang, L. Yang, P. Yin, X. Guan, G. Wang, J. Colloid Interface Sci. 2024, 658, 952.
