Template-Free Synthesis of Hierarchical Composite Nanotubes with Superior Lithium and Sodium Storage Performance
Zunxian Yang
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorJianhua Huang
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorYufei Zhang
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorBingqing Ye
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorShimin Lin
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorJiahui Liu
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorYuliang Ye
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorKang Zheng
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorGanzhen Lu
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorTailiang Guo
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorCorresponding Author
Xuebin Yu
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Department of Materials Science, Fudan University, Shanghai, 200433 P. R. China
Search for more papers by this authorZunxian Yang
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorJianhua Huang
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorYufei Zhang
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorBingqing Ye
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorShimin Lin
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorJiahui Liu
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorYuliang Ye
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorKang Zheng
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorGanzhen Lu
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorTailiang Guo
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorCorresponding Author
Xuebin Yu
National & Local United Engineering Laboratory of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350116 P. R. China
Department of Materials Science, Fudan University, Shanghai, 200433 P. R. China
Search for more papers by this authorAbstract
2D transition metal disulfides are one of the most preferred materials for lithium-/sodium-ion batteries (LIBs). However, complex processes and structural instability during cycling are challenges faced. Herein, the hierarchical composite nanotubes CeO2@C@MoS2 (MS/CNTs) are prepared by electrostatic spinning, followed by a simple carbon coating method. The as-prepared composite nanotubes with self-assembled layer structures are characterized by a more stable structure compared with traditional nanofibers due to the existence of a dense skeleton. As a result of the stable framework structure, MS/CNTs exhibit excellent electrochemical performance in LIBs (1002 mA hg−1 at 0.1 A g−1 and 690 mA hg−1 at 1 A g−1 after 500 cycles) and super-long cyclic stability and electrochemical performance (550 mA hg−1 at 2 A g−1 after 2400 cycles). MS/CNTs also show excellent storage performance in sodium batteries (440 mA hg−1 at 0.5 A g−1, 400 mA hg−1 at 1 A g−1). The stability of MoS2 nanotubes is effectively improved by chemical and physical methods, mainly due to the support of the CeO2@C, metal–organic framework (MOF) tube skeleton, which avoids the shedding of nanotubes after cycling, maintaining a unique structural topography even after 500 cycles.
Conflict of Interest
The authors declare no conflict of interest.
Supporting Information
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