Microporous Nitrogen-Rich Polymers via Ullmann Coupling Reaction for Selective Adsorption of C2H2 over CH4†
Jitao Huang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
College of Chemistry and Materials, Ningde Normal University, Ningde, Fujian, 352100 China
Search for more papers by this authorQinfang Peng
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorChulong Liu
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorYingxiang Ye
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorLiangji Chen
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorYuanchao Lv
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorYisi Yang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorShimin Chen
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorFahui Xiang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorHao Zhang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorCorresponding Author
Zhangjing Zhang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
E-mail: [email protected], [email protected]Search for more papers by this authorCorresponding Author
Shengchang Xiang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
E-mail: [email protected], [email protected]Search for more papers by this authorJitao Huang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
College of Chemistry and Materials, Ningde Normal University, Ningde, Fujian, 352100 China
Search for more papers by this authorQinfang Peng
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorChulong Liu
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorYingxiang Ye
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorLiangji Chen
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorYuanchao Lv
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorYisi Yang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorShimin Chen
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorFahui Xiang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorHao Zhang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
Search for more papers by this authorCorresponding Author
Zhangjing Zhang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
E-mail: [email protected], [email protected]Search for more papers by this authorCorresponding Author
Shengchang Xiang
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, Fujian, 350007 China
E-mail: [email protected], [email protected]Search for more papers by this author† Dedicated to the Special Issue of Emerging Investigators in 2022.
Comprehensive Summary
Acetylene purification from methane is challenging in the field of porous organic polymers (POPs). Herein, we have provided one-pot Ullmann coupling reaction to synthesize a series of POPs with rich N-sites, named FJU-POP-n, wherein the low-cost and non-toxic Cu(acac)2 and environmental-friendly glycerol are employed as catalyst and solvent, respectively. These POPs constructed by aromatic amine and haloarene monomers exhibit different steric configurations and pore sizes. Among these, FJU-POP-4 with abundant N-functional sites and suitable pore size exhibits ultra-high selective separation for C2H2/CH4 (307.1, 50 : 50) at ambient conditions, the highest among the reported MOFs and POPs with nitrogen-sites as only functional species. Dynamic fixed bed breakthrough and regeneration experiments confirm structural stability and reproducibility, indicating their promising application in selective separation.
Supporting Information
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| cjoc202200397-sup-0001-Supinfo.pdfPDF document, 6.3 MB |
Appendix S1: Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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