Lewis Acid Enables Ketone Phosphorylation: Synthesis of Alkenyl Phosphonates
Corresponding Author
Xiao-Hong Wei
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
E-mail: [email protected]; [email protected]Search for more papers by this authorChun-Yuan Bai
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorLian-Biao Zhao
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorPing Zhang
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorZhen-Hua Li
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorYan-Bin Wang
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorCorresponding Author
Qiong Su
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
E-mail: [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Xiao-Hong Wei
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
E-mail: [email protected]; [email protected]Search for more papers by this authorChun-Yuan Bai
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorLian-Biao Zhao
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorPing Zhang
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorZhen-Hua Li
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorYan-Bin Wang
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
Search for more papers by this authorCorresponding Author
Qiong Su
Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, No. 1, Northwest Xincun, Lanzhou, Gansu, 730030 China
E-mail: [email protected]; [email protected]Search for more papers by this authorMain observation and conclusion
An efficient Lewis acid enabled ketones phosphonylation to synthesize vinylphosphonates has been developed. This method relays on ketone hydrophosphonylation/α-hydroxy phosphonates unimolecular elimination (E1) dehydration cascade reaction sequence. Various C—P bond formation products were obtained in moderate to excellent yields with water as the only byproduct in the reaction.
Supporting Information
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Appendix S1: Supporting Information |
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