Concise Report
Ruthenium(II) Complexes Bearing Schiff Base Ligands for Efficient Acceptorless Dehydrogenation of Secondary Alcohols†
Zhiqiang Hao,
Kang Liu,
Qi Feng,
Qing Dong,
Dongzhu Ma,
Zhangang Han,
Guo-Liang Lu,
Jin Lin,
Zhiqiang Hao
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorKang Liu
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorQi Feng
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorQing Dong
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorCorresponding Author
Dongzhu Ma
Department of Environment and Chemical Engineering, Hebei College of Industry and Technology, Shijiazhuang, Hebei, 050091 China
E-mail: [email protected], [email protected]Search for more papers by this authorZhangang Han
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorGuo-Liang Lu
Auckland Cancer Society Research Centre, Faculty of Medical and Health Sciences, The University of Auckland, Private Bag 92019, Auckland, 1142 New Zealand
Search for more papers by this authorCorresponding Author
Jin Lin
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
E-mail: [email protected], [email protected]Search for more papers by this authorZhiqiang Hao,
Kang Liu,
Qi Feng,
Qing Dong,
Dongzhu Ma,
Zhangang Han,
Guo-Liang Lu,
Jin Lin,
Zhiqiang Hao
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorKang Liu
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorQi Feng
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorQing Dong
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorCorresponding Author
Dongzhu Ma
Department of Environment and Chemical Engineering, Hebei College of Industry and Technology, Shijiazhuang, Hebei, 050091 China
E-mail: [email protected], [email protected]Search for more papers by this authorZhangang Han
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
Search for more papers by this authorGuo-Liang Lu
Auckland Cancer Society Research Centre, Faculty of Medical and Health Sciences, The University of Auckland, Private Bag 92019, Auckland, 1142 New Zealand
Search for more papers by this authorCorresponding Author
Jin Lin
Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050024 China
E-mail: [email protected], [email protected]Search for more papers by this authorDedicated to the 30th Anniversary of State Key Laboratory of Organometallic Chemistry.
Abstract
Four ruthenium(II) complexes 1—4 [RN=CH-(2,4-(tBu)2C6H2O)]RuH(PPh3)2(CO) (R = C6H5, 1; R = 4-MeC6H4, 2; R = 4-ClC6H4, 3; R = 4-BrC6H4, 4) bearing Schiff base ligands were prepared by treating RuHClCO(PPh3)3 with RN=CH-(2,4-(tBu)2C6H2OH (L1—L4) in the presence of triethylamine. Their structures were fully characterized by elemental analysis, IR, NMR spectroscopy and X-ray crystallography. These Ru(II) complexes exhibit high catalytic performance and good functional-group compatibility in the acceptorless dehydrogenation of secondary alcohols, affording the corresponding ketones in 82%—94% yields.
Supporting Information
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Appendix S1: Supporting Information |
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