Nitrogen-Doped Nanoporous Carbons through Direct Carbonization of a Metal-Biomolecule Framework for Supercapacitor
Jianhui Zhang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
Department of Chemistry and Pharmacy, Zhuhai College of Jilin University, Zhuhai, Guangdong 519041, China
Search for more papers by this authorCorresponding Author
Daliang Zhang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, ChinaSearch for more papers by this authorGuanghui Dai
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
Search for more papers by this authorQianrong Fang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
Search for more papers by this authorCorresponding Author
Shilun Qiu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, ChinaSearch for more papers by this authorJianhui Zhang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
Department of Chemistry and Pharmacy, Zhuhai College of Jilin University, Zhuhai, Guangdong 519041, China
Search for more papers by this authorCorresponding Author
Daliang Zhang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, ChinaSearch for more papers by this authorGuanghui Dai
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
Search for more papers by this authorQianrong Fang
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
Search for more papers by this authorCorresponding Author
Shilun Qiu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, China
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012, ChinaSearch for more papers by this authorAbstract
Nitrogen-doped nanoporous carbons have been successfully synthesized by direct carbonization of a nitrogen- rich metal-biomolecule framework, zinc glutamate (Zn(H2O)(C5H7NO4)·H2O), as a template without any additional carbon or nitrogen sources. The surface area and pore size distribution of the resultant carbon materials were studied based on the carbonization temperature. These carbons exhibited high specific surface area (as high as 1619.2 m2·g−1 for ZGC-1000). Furthermore, ZGC-1000 also provided a large specific capacitance of 140.8 F·g−1 at a current density of 0.25 A·g−1 when measured in a three-electrode system. It is believed that the presence of the nitrogen-doped nanoporous carbons prepared from the metal-organic frameworks will further facilitate the exploration of such materials as supercapacitors.
REFERENCES
- 1 Zhai, Y.; Dou, Y.; Zhao, D. Y.; Fulvio, P. F.; Mayes, R. T.; Dai, S.. Adv. Mater., 2011, 23, 4828.
- 2 Kaskhedikar, N. A.; Maier, J.. Adv. Mater., 2009, 21, 2664.
- 3 Jorda-Beneyto, M.; Suarez-Garcia, F.; Lozano-Castello, D.; Cazorla-Amoros, D.; Linares-Solano, A.. Carbon, 2007, 45, 293.
- 4 Calvino, V.; Lopez, A. J.; Duran, C. J.; Martin, R. M.. Catal. Rev.: Sci. Eng., 2010, 52, 325.
- 5 Liu, J.; Wickramaratne, N. P.; Qiao, S. Z.; Jaroniec, M.. Nat. Mater., 2015, 14, 763.
- 6 Salunkhe, R. R.; Tang, J.; Kamachi, Y.; Nakato, T.; Kim, J. H.; Yamauchi, Y.. ACS Nano, 2015, 9, 6288.
- 7 Wang, L.; Feng, X.; Ren, L. T.; Piao, Q. H.; Zhong, J. Q.; Wang, Y. B.; Li, H. W.; Chen, Y. F.; Wang, B.. J. Am. Chem. Soc., 2015, 137, 4920.
- 8 Shen, W.; Fan, W.. J. Mater. Chem. A, 2013, 1, 999.
- 9 Su, F.; Poh, C. K.; Chen, J. S.; Xu, G.; Wang, D.; Li, Q.; Lin, J.; Lou, X. W.. Energy Environ. Sci., 2011, 4, 717.
- 10 Chen, L. F.; Zhang, X. D.; Liang, H. W.; Kong, M.; Guan, Q. F.; Chen, P.; Wu, Z. Y.; Yu, S. H.. ACS Nano, 2012, 6, 7092.
- 11 Li, T. T.; Yang, G. W.; Wang, J.; Zhou, Y. Y.; Han, H. Y.. J. Solid State Electrochem., 2013, 10, 2651.
- 12 Yang, S.; Xu, G.-Y.; Han, J.-P.; Bing, H.; Dou, H.; Zhang, X.-G.. Acta Phys.-Chim. Sin., 2015, 31, 685.
- 13 Chen, X. Y.; Chen, C.; Zhang, Z. J.; Xie, D. H.; Deng, X.; Liu, J. W.. J. Power Sources, 2013, 230, 50.
- 14 Hu, B.; Wang, K.; Wu, L. H.; Yu, S. H.; Antonietti, M.; Titirici, M.. Adv. Mater., 2010, 22, 1.
- 15 Horikawa, T.; Sakao, N.; Sekida, T.; Hayashi, J.; Do, D. D; Katoh, M.. Carbon, 2012, 50, 1833.
- 16 Chaikittisilp, W.; Ariga, K.; Yamauchi, Y.. J. Mater. Chem. A, 2013, 1, 14.
- 17 Li, S. L.; Xu, Q.. Energy Environ. Sci., 2013, 6, 1656.
- 18 Liu, B.; Shioyama, H.; Jiang, H.; Zhang, H. X.; Xu, Q.. Carbon, 2010, 48, 456.
- 19 Yang, S. J.; Kim, T.; Im, J. H.; Kim, Y. S.; Lee, K.; Jung, H.; Park, C. R.. Chem. Mater., 2012, 24, 464.
- 20 Lim, S. K.; Suh, K.; Kim, Y.; Yoon, M.; Park, H.; Dybtsev, D. N.; Kim, K.. Chem. Commun., 2012, 48, 7447.
- 21 Han, Y. Z.; Qi, P. F.; Li, S. W.; Feng, X.; Zhou, J. W.; Li, H. W.; Su, S. Y.; Li, X. G.; Wang, B.. Chem. Commun., 2014, 50, 8057.
- 22 Torad, N. L.; Li, Y. Q.; Ishihara, S.; Ariga, K.; Kamachi, Y.; Lian, H. Y.; Hamoudi, H.; Sakka, Y.; Chaikittisilp, W.; Wu, K. C.-W.; Yamauchi, Y.. Chem. Lett., 2014, 43, 717.
- 23 Malgras, V.; Ji, Q. M.; Kamachi, Y.; Mori, T.; Shieh, F.-K.; Wu, K. C. W.; Ariga, K.; Yamauchi, Y.. Bull. Chem. Soc. Jpn., 2015, 88, 1171.
- 24 Chaikittisilp, W.; Hu, M.; Wang, H.; Huang, H.-S.; Fujita, T.; Wu, K. C.-W.; Chen, L.-C.; Yamauchi, Y.; Ariga, K.. Chem. Commun., 2012, 48, 7259.
- 25 Hu, J.; Wang, H.; Gao, Q.; Guo, H.. Carbon, 2010, 48, 3599.
- 26 Proch, S.; Villanueva, J.; Irrgang, T.; D?ring, C.; Kempe, R.. Z. Kristallogr. NCS, 2008, 223, 55.
- 27 Tang, J.; Salunkhe, R. R.; Liu, J.; Torad, N. L.; Imura, M.; Furukawa, S.; Yamauchi, Y.. J. Am. Chem. Soc., 2015, 137, 1572.
- 28 Jiang, H. L.; Liu, B.; Lan, Y. Q.; Kuratani, K.; Akita, T.; Shioyama, H.; Zong, F. Q.; Xu, Q.. J. Am. Chem. Soc., 2011, 133, 11854.
- 29 Liu, B.; Shioyama, H.; Jiang, H. L.; Zhang, X. B.; Xu, Q.. Carbon, 2010, 48, 456.
- 30 Ferrari, A. C.; Robertson, J.. Phys. Rev. B, 2000, 61, 14095.
- 31 Sadezky, A.; Muckenhuber, H.; Grothe, H.; Niessner, R.; Pöschl, U.. Carbon, 2005, 43, 1731.
- 32 Wang, D. W.; Li, F.; Yin, L. C.; Lu, X.; Chen, Z. G.; Gentle, I. R.; Lu, G. Q.; Cheng, H. M.. Chem. Eur. J., 2012, 18, 5345.
- 33 Shen, W.; Li, Z.; Liu, Y.. Recent Patents Chem. Eng., 2008, 1, 27.
- 34 Zhai, Y.; Dou, Y.; Zhao, D.; Fulvio, P. F.; Mayes, R. T.; Dai, S.. Adv. Mater., 2011, 23, 4828.
- 35 Xu, B.; Duan, H.; Chu, M.; Cao, G.; Yang, Y.. J. Mater. Chem. A, 2013, 1, 4565.
- 36 Zhao, L.; Fan, L. Z.; Zhou, M. Q.; Guan, H.; Qiao, S.; Antonietti, M.; Titirici, M.-M.. Adv. Mater., 2010, 22, 5202.
- 37 Zhu, T.; Chen, J. S.; Lou, X. W.. J. Mater. Chem., 2010, 20, 7015.
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