Synthesis of Copillar[5]arenes and Their Host-Guest Complexation with Two Types of Guests
Hongfei Huang
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
Search for more papers by this authorCorresponding Author
Luzhi Liu
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, ChinaSearch for more papers by this authorCorresponding Author
Wengui Duan
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, ChinaSearch for more papers by this authorYan Huang
Guangxi Institute of Traditional Medical and Pharmaceutical Science, Nanning, Guangxi 530022, China
Search for more papers by this authorGuishan Lin
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
Search for more papers by this authorHongfei Huang
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
Search for more papers by this authorCorresponding Author
Luzhi Liu
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, ChinaSearch for more papers by this authorCorresponding Author
Wengui Duan
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, ChinaSearch for more papers by this authorYan Huang
Guangxi Institute of Traditional Medical and Pharmaceutical Science, Nanning, Guangxi 530022, China
Search for more papers by this authorGuishan Lin
School of Chemistry and Chemical Engineering, Guangxi University & Guangxi Experiment Centre of Science and Technology, Nanning, Guangxi 530004, China
Search for more papers by this authorAbstract
A series of novel copillar[5]arenes 1a–1f containing different substituents were synthesized. And their complexation with two types of guests was investigated. For symmetrical guests, 1,4-dibromobutane (DBB) could thread in the cavity of copillar[5]arenes to form inclusion complexes. But for the unsymmetrical guests, copillar[5]arene 1f bearing 4-(naphthalen-1-yloxy)butoxy could not complex with sec-butyl iodide (SBI) and sec-butyl bromide (SBB) at all, while 1f showed weak interaction with sec-butylamine·HCl (SBA) outside the cavity. These results indicated that the modified group of copillar[5]arene and the symmetry of guest played an important role in the complexation model and selectivity.
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