Crystal Structure and Host-Guest Binding Ability of Three Types of Pillar[5]arenes
Luzhi Liu
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China
Search for more papers by this authorWengui Duan
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China
Search for more papers by this authorYuhui Kou
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
Search for more papers by this authorLingyun Wang
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
Search for more papers by this authorHerbert Meier
Institute of Organic Chemistry, University of Mainz, Mainz 55099, Germany
Search for more papers by this authorCorresponding Author
Derong Cao
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China, Tel.: 0086-020-87110245; Fax: 0086-020-87110245Search for more papers by this authorLuzhi Liu
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China
Search for more papers by this authorWengui Duan
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China
Search for more papers by this authorYuhui Kou
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
Search for more papers by this authorLingyun Wang
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
Search for more papers by this authorHerbert Meier
Institute of Organic Chemistry, University of Mainz, Mainz 55099, Germany
Search for more papers by this authorCorresponding Author
Derong Cao
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China, Tel.: 0086-020-87110245; Fax: 0086-020-87110245Search for more papers by this authorAbstract
A systematic research of the structural characterization and the host-guest binding abilities between three types of pillar[5]arenes 3–5 (3 for Structure Type I, 4 for Structure Type II and 5 for Structure Type III) is carried out by 1H NMR measurements and X-ray study. The results show that the configurations or symmetry of their cavities not only have large difference in these three types of pillar[5]arenes, but also have more or less variations even in the same structure type or the same host locked different guests such as crystals of 3a–3b, 4a–4d. On the other hand, the complexation behavior of pillar[5]arenes with 1,4-dibromobutane (DBB) is affected by the different symmetrical structure or substituents on the rings.
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