One-Pot Synthesis of Aliphatic Nitro Compounds by Michael/retro-Claisen Fragmentation Domino Reaction
Wei Zhang
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Search for more papers by this authorYanjing Wang
College of Sciences, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorCuibing Bai
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Search for more papers by this authorJialong Wen
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Search for more papers by this authorCorresponding Author
Naixing Wang
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China, Tel.: 0086-010-82543575; Fax: 0086-010-62554670Search for more papers by this authorWei Zhang
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Search for more papers by this authorYanjing Wang
College of Sciences, Beijing University of Chemical Technology, Beijing 100029, China
Search for more papers by this authorCuibing Bai
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Search for more papers by this authorJialong Wen
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Search for more papers by this authorCorresponding Author
Naixing Wang
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China, Tel.: 0086-010-82543575; Fax: 0086-010-62554670Search for more papers by this authorAbstract
A novel and concise method for the construction of γ-nitro ketones and 1,3-dinitro compounds with chemoselective acyl transfer has been presented under basic conditions via one-pot reactions. These reactions feature high atom- and step-economic possess, mild condition and simple operation for one-pot synthesis of aliphatic nitro compounds. This protocol provides the products in good yields. The possible reaction mechanism has also been proposed.
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