Fluorescent Recognition of Small Organic Molecules Based on Supramolecular Aggregation/Deaggregation of Planar Cu(II) Coordination Complex
Liang Hao
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorTong Zhang
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorGe Chang
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorCorresponding Author
Hui Li
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China, Tel.: 0086-010-68914780; Fax: 0086-010-68914780-804Search for more papers by this authorLiang Hao
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorTong Zhang
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorGe Chang
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorCorresponding Author
Hui Li
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
Key Laboratory of Clusters Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China, Tel.: 0086-010-68914780; Fax: 0086-010-68914780-804Search for more papers by this authorAbstract
A Cu(II) coordination complex (1) with Schiff ligand derived from diaminomaleonitrile was synthesized and characterized, in which the ligand is rigid, planar and conjugated. The complex 1 displays an interesting fluorescent property relative to solvents which can be turned-on by CH2Cl2 and CHCl3 solvent molecules. The mechanism of this selective fluorescence emission has been studied based on the crystal structure and the spectrum analysis. The tuning on and off fluorescence of complex 1 can be controlled by the process of supramolecular aggregation/deaggregation in different solvents.
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