Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions
Jie Zhang
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorZengqiang Jiang
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorDan Zhao
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorGuozhen He
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorShuangli Zhou
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorCorresponding Author
Shiqing Han
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Key Laboratory of Synthetic Chemistry of Natural Products, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, China
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China, Tel.: 0086-025-58139970; Fax: 0086-025-58139369Search for more papers by this authorJie Zhang
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorZengqiang Jiang
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorDan Zhao
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorGuozhen He
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorShuangli Zhou
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Search for more papers by this authorCorresponding Author
Shiqing Han
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China
Key Laboratory of Synthetic Chemistry of Natural Products, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, China
College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, Jiangsu 211816, China, Tel.: 0086-025-58139970; Fax: 0086-025-58139369Search for more papers by this authorAbstract
An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical (TEMPO) in the presence of air, various alcohols could be converted into the corresponding aldehydes or ketones in good to excellent isolated yields under mild conditions.
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