Michael Addition Reaction of Fluorinated Nitro Compounds
Feng Huan
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorHuawei Hu
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Search for more papers by this authorCorresponding Author
Yangen Huang
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Yangen Huang, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China, Tel.: 0086-021-67792612; Fax: 0086-021-6779260
Yong Guo, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China, Tel.: 0086-021-54925462; Fax: 0086-021-64166128
Search for more papers by this authorQingyun Chen
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorCorresponding Author
Yong Guo
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Yangen Huang, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China, Tel.: 0086-021-67792612; Fax: 0086-021-6779260
Yong Guo, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China, Tel.: 0086-021-54925462; Fax: 0086-021-64166128
Search for more papers by this authorFeng Huan
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorHuawei Hu
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Search for more papers by this authorCorresponding Author
Yangen Huang
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Yangen Huang, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China, Tel.: 0086-021-67792612; Fax: 0086-021-6779260
Yong Guo, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China, Tel.: 0086-021-54925462; Fax: 0086-021-64166128
Search for more papers by this authorQingyun Chen
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorCorresponding Author
Yong Guo
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Yangen Huang, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China, Tel.: 0086-021-67792612; Fax: 0086-021-6779260
Yong Guo, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China, Tel.: 0086-021-54925462; Fax: 0086-021-64166128
Search for more papers by this authorAbstract
The Michael addition reactions of fluorinated nitro compounds with electron deficient olefins to give γ-fluoro-γ-nitro-esters, nitriles and ketones which bear a fluorinated quaternary carbon center were reported. The reactions were promoted by TMG, affording the desired adducts in acceptable to good yields.
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