Synthesis, Crystal Structure and Thermochemical Properties of a One-Dimensional Chain Complex [Cd(succ)PIP]n
Xia Li
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorWenjie Zhao
Department of Biochemical Engineering, Xianyang Vocational Technical College, Xianyang, Shaanxi 712000, China
Search for more papers by this authorFei Liu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorJinting Tan
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorXing Feng
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorYingli Lu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorCorresponding Author
Xuwu Yang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China, Tel.: 0086-029-88302054; Fax: 0086-029-88303798Search for more papers by this authorXia Li
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorWenjie Zhao
Department of Biochemical Engineering, Xianyang Vocational Technical College, Xianyang, Shaanxi 712000, China
Search for more papers by this authorFei Liu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorJinting Tan
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorXing Feng
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorYingli Lu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorCorresponding Author
Xuwu Yang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China, Tel.: 0086-029-88302054; Fax: 0086-029-88303798Search for more papers by this authorAbstract
A new complex, [Cd(succ)PIP]n (PIP=2-phenyl-imidazo[4,5-f]1,10-phenanthroline, H2-succ=succinate), was synthesized and characterized by X-ray crystallography, elemental analysis, and TG-DTG. The results show that the complex crystallizes in an orthorhombic space group Pcca; a=14.065(2) Å, b=9.901(8) Å, c=28.933(2) Å and Z=8. The structure of the complex is one-dimensional chain [Cd(succ)PIP]n, and each Cd2+ is five-coordinated by two chelating nitrogen atoms from one PIP ligand, three oxygen atoms from three different succ dianionic ligands to form a distorted trigonal-bipyramida geometry. The constant-volume combustion energy of the complex, ΔcU, was determined by an intelligent micro-rotating-bomb calorimeter (IMRBC-type I) at 298.15 K. Then the standard molar enthalpy of combustion, ΔcHm⊖, and the standard molar enthalpy of formation, ΔfHm⊖ have been calculated.
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