Volume 25, Issue 4 pp. 498-502

Full Paper

Synthesis, Crystal Structures and Properties of Two Novel Co(II) and Cd(II) Complexes of N-Acetyl-L-glutamic Acid and Imidazole Ligands

Meng-Qi Cheng,

Meng-Qi Cheng

Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, China

Department of Chemistry, Anshun Teacher's College, Anshun, Guizhou 561000, China

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Lu-Fang Ma,

Lu-Fang Ma

Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, China

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Li-Ya Wang,

Li-Ya Wang

[email protected]

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Meng-Qi Cheng,

Meng-Qi Cheng

Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, China

Department of Chemistry, Anshun Teacher's College, Anshun, Guizhou 561000, China

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Lu-Fang Ma,

Lu-Fang Ma

Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, China

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Li-Ya Wang,

Li-Ya Wang

[email protected]

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First published: 05 April 2007

https://doi.org/10.1002/cjoc.200790093

Citations: 4

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Abstract

Two novel complexes {(Co(A-glu)(Im)₂(·0.5H₂O}_n (1) and (Cd(A-glu)(Im)₃(_n (2) (H₂A-gluN-acetyl-L-glu- tamic acid, Im=imidazole) have been synthesized from the reaction of H₂A-glu with Co(CH₃COO)₂·4H₂O or Cd(CH₃COO)₂·2H₂O in the presence of Im. Both of the complexes display different coordination environment and similar one-dimensional chain structure. The magnetic susceptibility measurements for 1 show a weak antiferromagnetic interaction between two cobalt(II) ions bridged by A-glu ligand. The complex 2 exhibits an intense fluorescent emission in solid state at room temperature.

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Volume25, Issue4

April, 2007

Pages 498-502

Synthesis, Crystal Structures and Properties of Two Novel Co(II) and Cd(II) Complexes of N-Acetyl-L-glutamic Acid and Imidazole Ligands

Abstract

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Synthesis, Crystal Structures and Properties of Two Novel Co(II) and Cd(II) Complexes of N-Acetyl-L-glutamic Acid and Imidazole Ligands

Abstract

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