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Nickel-catalyzed Electrochemical Coupling of Phenyl Halide and Study of Mechanism

Peng Zhao

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Yi-Wen Luo,

Yi-Wen Luo

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Teng Xue,

Teng Xue

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Ai-Jian Zhang,

Ai-Jian Zhang

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Jia-Xing Lu,

Jia-Xing Lu

[email protected]

Project supported by the National Natural Science Foundation of China (No. 20573037) and the Natural Science Foundation of Shanghai (No. 05JC14070).

Tel.: 0086-021-62233491

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Peng Zhao,

Peng Zhao

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Yi-Wen Luo,

Yi-Wen Luo

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Teng Xue,

Teng Xue

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

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Ai-Jian Zhang,

Ai-Jian Zhang

Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China

Search for more papers by this author

Jia-Xing Lu,

Jia-Xing Lu

[email protected]

Project supported by the National Natural Science Foundation of China (No. 20573037) and the Natural Science Foundation of Shanghai (No. 05JC14070).

Tel.: 0086-021-62233491

Search for more papers by this author

First published: 04 July 2006

https://doi.org/10.1002/cjoc.200690167

Citations: 9

Project supported by the National Natural Science Foundation of China (No. 20573037) and the Natural Science Foundation of Shanghai (No. 05JC14070).

Tel.: 0086-021-62233491

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Abstract

Electrochemical coupling of phenyl halide catalyzed by NiCl₂bpy in DMF has been investigated in this paper. Stainless steel was used as cathode and zinc as anode. Effects of potential, temperature and catalyst on electrolyses were studied to optimize the electrolytic conditions, with the maximal isolated yield under potentiostatic electrolysis to be 85%. Cyclic voltammetry of NiCl₂bpy in the presence of phenyl bromide has been studied and mechanisms, concerned with several kinds of nickel complex, have been summarized.

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Volume24, Issue7

July, 2006

Pages 877-880

Nickel-catalyzed Electrochemical Coupling of Phenyl Halide and Study of Mechanism

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Nickel-catalyzed Electrochemical Coupling of Phenyl Halide and Study of Mechanism

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