Synthesis and Structural Characterization of Two Lead(II) Complexes of Bis(3,5-dimethylpyrazolyl)methane
Qiao-Yun Li
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500, China
Search for more papers by this authorWen-Hua Zhang
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorHong-Xi Li
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorZhi-Gang Ren
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorYong Zhang
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorJian-Ping Lang
Project supported by the National Natural Science Foundation of China (Nos. 20271036, 20525101), Natural Science Foundation of Jiangsu Province (No. BK2004205), and the Research Funds (No. 20050285004) for the Doctoral Program of Higher Education of China.
Tel.: 0086-0512-65882865; Fax: 0086-0512-65880089
Search for more papers by this authorQiao-Yun Li
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500, China
Search for more papers by this authorWen-Hua Zhang
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorHong-Xi Li
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorZhi-Gang Ren
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorYong Zhang
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorJian-Ping Lang
Project supported by the National Natural Science Foundation of China (Nos. 20271036, 20525101), Natural Science Foundation of Jiangsu Province (No. BK2004205), and the Research Funds (No. 20050285004) for the Doctoral Program of Higher Education of China.
Tel.: 0086-0512-65882865; Fax: 0086-0512-65880089
Search for more papers by this authorProject supported by the National Natural Science Foundation of China (Nos. 20271036, 20525101), Natural Science Foundation of Jiangsu Province (No. BK2004205), and the Research Funds (No. 20050285004) for the Doctoral Program of Higher Education of China.
Tel.: 0086-0512-65882865; Fax: 0086-0512-65880089
Abstract
Reactions of lead(II) nitrate or perchlorate with bis(3,5-dimethylpyrazolyl)methane (dmpzm), produced two new Pb(II) chelated complexes [Pb(dmpzm)2X2] (X=NO−3 1, ClO−4 2). Both compounds were structurally characterized by elemental analysis, IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. Both compounds are mononuclear with a distorted square antiprismatic PbN4O4 coordination geometry incorporating a pair of O,O′-bidentate anions and N,N′-bidentate dmpzm ligands. In the crystals of 1 or 2, the methyl or methylene groups of dmpzm ligand interact with the oxygen atoms of nitrates or perchlorates to afford intra- and intermolecular hydrogen bonding, thereby forming a two-dimensional network 1 or a three-dimensional structure 2.
REFERENCES
- 1 Engelhardt, L. M.; Harrowfield, J. M.; Miyamae, H.; Patrick, J. M.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1111.
- 2 Bytheway, I.; Engelhardt, L. M.; Harrowfield, J. M.; Kepert, D. L.; Miyamae, H.; Patrick, J. M.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1099.
- 3 Mann, K. L. V.; Jeffery, J. C.; McCleverty, J. A.; Thornton, P.; Ward, M. D.. J. Chem. Soc., Dalton Trans., 1998, 89.
- 4 Jones, P. L.; Mann, K. L. V.; Jeffery, J. C.; McCleverty, J. A.; Ward, M. D.. Polyhedron, 1997, 16, 2435.
- 5 Psillakis, E.; Jeffery, J. C.; McCleverty, J. A.; Ward, M. D.. Chem. Commun., 1997, 1965.
- 6 Mann, K. L. V.; Jeffery, J. C.; McCleverty, J. A.; Ward, M. D.. J. Chem. Soc., Dalton Trans., 1998, 3029.
- 7 Psillakis, E.; Jeffery, J. C.; McCleverty, J. A.; Ward, M. D.. J. Chem. Soc., Dalton Trans., 1997, 1645.
- 8 Reger, D. L.; Huff, M. F.; Rheingold, A. L.; Haggerty, B. S.. J. Am. Chem. Soc., 1992, 114, 579.
- 9 Aghabozorg, H.; Palenik, K. C.; Palenik, G. J.. Inorg. Chim. Acta, 1986, 111, 253.
- 10 Tsubomura, T.; Ito, M.; Sakai, K.. Inorg. Chim. Acta, 1999, 284, 149.
- 11 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1127.
- 12 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1029.
- 13 Harrowfield, J. M.; Miyamae, H.; Shand, T. M.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1043.
- 14 Harrowfield, J. M.; Miyamae, H.; Shand, T. M.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1051.
- 15 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1067.
- 16 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1081.
- 17 Harrowfield, J. M.; Miyamae, H.; Shand, T. M.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1089.
- 18 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1121.
- 19 Engelhardt, L. M.; Harrowfield, J. M.; Miyamae, H.; Patrick, J. M.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1135.
- 20 Harrowfield, J. M.; Kapert, D. L.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1147.
- 21 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1157.
- 22 Harrowfield, J. M.; Miyamae, H.; Skelton, B. W.; Soudi, A. A.; White, A. H.. Aust. J. Chem., 1996, 49, 1165.
- 23 Fenton, D. E.; Mattens, R. W.; McPartlin, M.; Murphy, B. P.; Scowen, I. J.; Tasker, P. A.. J. Chem. Soc., Dalton Trans., 1996, 3421.
- 24 Esteban, D.; Banobre, D.; de Blas, A.; Rodriguez-Blas, T.; Bastida, R.; Macias, A.; Rodriguez, A.; Fenton, D. E.; Adams, H.; Mahia, J.. Eur. J. Inorg. Chem., 2000, 1445.
- 25 Sobanska, S.; Wignacourt, J. P.; Conflant, P.; Drache, M.; Lagrenee, M.; Holt, E. M.. New J. Chem., 1999, 23, 393.
- 26 Stancia, C.; Hino, S. S.; Stender, M.; Richurds, A. F.; Olmstead, M. M.; Power, P. P.. Inorg. Chem., 2005, 44, 2774.
- 27 Pettinari, C.; Pettinari, R.. Coord. Chem. Rev., 2005, 249, 663.
- 28 Atkinson, I. M.; Chartres, J. D.; Everett, G. W.; Ji, X. K.; Lindoy, L. F.; Matthews, O. A.; Meehan, G. V.; Skelton, B. W.; Wei, G.; White, A. H.. J. Chem. Soc., Dalton Trans., 2000, 1191.
- 29 Hambley, T. W.; Lindoy, L. F.; Reimers, J. R.; Turner, P.; Wei, G.; Widmer-Copper, A. N.. J. Chem. Soc., Dalton Trans., 2001, 614.
- 30 Tei, L.; Blake, A. J.; Bencini, A.; Valtancoli, B.; Wilson, C.; Schröder, M.. J. Chem. Soc., Dalton Trans., 2000, 4122.
- 31 Julia, S.; Sala, P.; del Mazo, J.; Sancho, M.; Ochoa, C.; Elguero, J.; Fayet, J. P.; Vertut, M. C.. J. Heterocycl. Chem., 1982, 19, 1141.
- 32 Sheldrick, G. M., SHELXS-97 and SHELXL-97: Programs for Crystal Structure Solutions, University of Göttingen, Germany, 1997.
- 33 Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1993, p. 92.
- 34 Barron, P. F.; Dyason, J. C.; Healy, P. C.; Engelhardt, L. M.; Skelton, B. W.; White, A. H.. J. Chem. Soc., Dalton Trans., 1986, 1965.
- 35 Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A: Theory and Applications to Inorganic Chemistry, 5th ed., Wiley, New York, 1997, p. 199.
