Chemical Absorption of Carbon Dioxide Using Aqueous Piperidine Derivatives
Dong Jun Park
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Korea University, Department of Chemical and Biological Engineering, 145 Anam-ro, Seongbuk-gu, 136-713 Seoul, Republic of Korea
Search for more papers by this authorJeong Ho Choi
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Korea University, Department of Chemical and Biological Engineering, 145 Anam-ro, Seongbuk-gu, 136-713 Seoul, Republic of Korea
Search for more papers by this authorYoung Eun Kim
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Search for more papers by this authorSung Chan Nam
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Search for more papers by this authorKi Bong Lee
Korea University, Department of Chemical and Biological Engineering, 145 Anam-ro, Seongbuk-gu, 136-713 Seoul, Republic of Korea
Search for more papers by this authorCorresponding Author
Yeo Il Yoon
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Correspondence: Yeo Il Yoon ([email protected]), Korea Institute of Energy Research, Greenhouse Gas Laboratory, 152, Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.Search for more papers by this authorDong Jun Park
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Korea University, Department of Chemical and Biological Engineering, 145 Anam-ro, Seongbuk-gu, 136-713 Seoul, Republic of Korea
Search for more papers by this authorJeong Ho Choi
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Korea University, Department of Chemical and Biological Engineering, 145 Anam-ro, Seongbuk-gu, 136-713 Seoul, Republic of Korea
Search for more papers by this authorYoung Eun Kim
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Search for more papers by this authorSung Chan Nam
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Search for more papers by this authorKi Bong Lee
Korea University, Department of Chemical and Biological Engineering, 145 Anam-ro, Seongbuk-gu, 136-713 Seoul, Republic of Korea
Search for more papers by this authorCorresponding Author
Yeo Il Yoon
Korea Institute of Energy Research, Greenhouse Gas Laboratory,, 152, Gajeong-ro, Yuseong-gu, 305-343 Daejeon, Republic of Korea
Correspondence: Yeo Il Yoon ([email protected]), Korea Institute of Energy Research, Greenhouse Gas Laboratory, 152, Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea.Search for more papers by this authorAbstract
The heat of CO2 absorption is one of the important factors determining the operating cost of the CO2 absorption process when using aqueous amine solutions. Aqueous monoethanolamine (MEA) solution is a commercial absorbent, but has several drawbacks. Although piperidine (PIPD) has a high heat of absorption, it shows good CO2 absorption performance, including a high rate of CO2 absorption and a high CO2 loading capacity in comparison to MEA. PIPD derivatives were selected to identify the effect of functional groups of PIPD on the CO2 loading and heat of absorption. Introduction of a methyl group to the PIPD molecule increased the heat of absorption, whereas a hydroxyl group reduced it. The results indicate that the introduction of functional groups in particular positions could provide advantages in CO2 absorption and stripping performance.
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