Review
Recent Advances in Catalyst Development for Enhanced p-Xylene Production via Toluene Methylation
Kanchan Guru,
Nandana Chakinala,
Anand G. Chakinala,
Praveen K. Surolia,
Kanchan Guru
Department of Chemistry, Solar Energy Conversion and Nanomaterials Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
Search for more papers by this authorNandana Chakinala
Department of Chemical Engineering, Chemical Reaction Engineering Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
Search for more papers by this authorCorresponding Author
Anand G. Chakinala
Department of Chemical Engineering, Chemical Reaction Engineering Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Praveen K. Surolia
Department of Chemistry, Solar Energy Conversion and Nanomaterials Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
E-mail: [email protected]; [email protected]
Search for more papers by this authorKanchan Guru,
Nandana Chakinala,
Anand G. Chakinala,
Praveen K. Surolia,
Kanchan Guru
Department of Chemistry, Solar Energy Conversion and Nanomaterials Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
Search for more papers by this authorNandana Chakinala
Department of Chemical Engineering, Chemical Reaction Engineering Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
Search for more papers by this authorCorresponding Author
Anand G. Chakinala
Department of Chemical Engineering, Chemical Reaction Engineering Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Praveen K. Surolia
Department of Chemistry, Solar Energy Conversion and Nanomaterials Laboratory, Manipal University Jaipur, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, 303007 India
E-mail: [email protected]; [email protected]
Search for more papers by this authorFirst published: 28 June 2025
Abstract
p-Xylene is a key industrial chemical with increasing demand due to the shift in global markets toward petrochemicals. Although most p-xylene is currently produced through naphtha cracking or naphtha reforming, alternative and cost-effective manufacturing techniques are needed. Catalytic methylation of toluene using shape selective catalysts is a potential route to yield xylenes with great para selectivity. Recent research has focused on modifying catalysts to increase surface acidity, pore channels, and crystallinity, improving para selectivity and toluene conversion. However, challenges remain in designing effective shape selective catalysts without sacrificing catalytic activity and maximizing methanol utilization for increased p-xylene productivity. This review discusses recent developments in catalyst design and modification strategies for improved shape selectivity, including the influence of reaction conditions, kinetics, mechanism, and catalyst deactivation. The review concludes with a forward-looking perspective on developing, designing, and modifying catalysts to address gaps in the related research field.
Conflicts of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
There are no data to disclose.
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