Research Article

Chemical Diversity of Essential Oils from Asteriscus graveolens (Forssk.) Less.: Identification of cis-8-Acetoxychrysanthenyl Acetate as a New Natural Component

Gregory Cristofari

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

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Mohamed Znini,

Mohamed Znini

Laboratoire des Substances Naturelles & Synthèse et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco

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Lhou Majidi,

Lhou Majidi

Laboratoire des Substances Naturelles & Synthèse et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco

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Hamid Mazouz,

Hamid Mazouz

Laboratoire de Protection & Amélioration et Ecophysiologie Végétale, Faculté des Sciences et Techniques, Errachidia, Morocco

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Pierre Tomi,

Pierre Tomi

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

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Jean Costa,

Jean Costa

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

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Julien Paolini,

Corresponding Author

Julien Paolini

[email protected]

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)Search for more papers by this author

Gregory Cristofari,

Gregory Cristofari

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

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Mohamed Znini,

Mohamed Znini

Laboratoire des Substances Naturelles & Synthèse et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco

Search for more papers by this author

Lhou Majidi,

Lhou Majidi

Laboratoire des Substances Naturelles & Synthèse et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco

Search for more papers by this author

Hamid Mazouz,

Hamid Mazouz

Laboratoire de Protection & Amélioration et Ecophysiologie Végétale, Faculté des Sciences et Techniques, Errachidia, Morocco

Search for more papers by this author

Pierre Tomi,

Pierre Tomi

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

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Jean Costa,

Jean Costa

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

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Julien Paolini,

Corresponding Author

Julien Paolini

[email protected]

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)

Université de Corse, CNRS UMR 6134, Laboratoire de Chimie des Produits Naturels, FR-BP 52 Corte, (phone: +33-4 95 45 01 93; fax: +33-4 95 45 01 62)Search for more papers by this author

First published: 11 April 2012

https://doi.org/10.1002/cbdv.201100118

Citations: 15

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Abstract

Asteriscus graveolens is an endemic medicinal plant mainly distributed in south-western Algeria and south-eastern Morocco. The essential oils of leaves, stems, and flowers of A. graveolens had been studied by GC, GC/MS, and ¹³C-NMR. The spectral data of two nerolidol derivatives, 6-oxo- and 6-hydroxycyclonerolidol, were reassigned by 1D- and 2D-NMR spectroscopy. These compounds can be considered as chemical markers of this genus. The structure of a monoterpenic diester with a chrysanthenane skeleton, i.e., cis-8-acetoxychrysanthenyl acetate, was determined for the first time on the basis of GC/MS, and 1D- and 2D-NMR. The stem and leaf oils were characterized by high content of oxygenated sesquiterpenes with 6-oxo- and 6-hydroxycyclonerolidol as major components, and the flower essential oils were dominated by the new monoterpenic compound cis-8-acetoxychrysanthenyl acetate.

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Volume9, Issue4

April 2012

Pages 727-738

Chemical Diversity of Essential Oils from Asteriscus graveolens (Forssk.) Less.: Identification of cis-8-Acetoxychrysanthenyl Acetate as a New Natural Component

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Chemical Diversity of Essential Oils from Asteriscus graveolens (Forssk.) Less.: Identification of cis-8-Acetoxychrysanthenyl Acetate as a New Natural Component

Abstract

Graphical Abstract

References

Citing Literature

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