RESEARCH ARTICLE

Electrically-assisted chemical vapor polymerization: A novel method for in situ polymerization of pyrrole

Ankur Shukla

orcid.org/0000-0002-6298-8398

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, India

Contribution: Data curation (lead), Investigation (lead), Methodology (equal), Validation (equal), Visualization (lead), Writing - original draft (lead)

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Dipayan Das,

Corresponding Author

Dipayan Das

[email protected]

orcid.org/0000-0001-6049-7440

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, India

Correspondence

Dipayan Das, Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.

Email: [email protected]

Contribution: Conceptualization (equal), Data curation (equal), Formal analysis (equal), Investigation (equal), Methodology (equal), Supervision (lead), Validation (equal), Visualization (equal), Writing - review & editing (lead)

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Kushal Sen,

Kushal Sen

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, India

Contribution: Conceptualization (equal), Data curation (equal), Formal analysis (lead), Investigation (equal), Methodology (equal), Supervision (equal), Validation (equal), Writing - review & editing (equal)

Search for more papers by this author

Ankur Shukla,

Ankur Shukla

orcid.org/0000-0002-6298-8398

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, India

Contribution: Data curation (lead), Investigation (lead), Methodology (equal), Validation (equal), Visualization (lead), Writing - original draft (lead)

Search for more papers by this author

Dipayan Das,

Corresponding Author

Dipayan Das

[email protected]

orcid.org/0000-0001-6049-7440

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, India

Correspondence

Dipayan Das, Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.

Email: [email protected]

Search for more papers by this author

Kushal Sen,

Kushal Sen

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, India

Search for more papers by this author

First published: 25 November 2022

https://doi.org/10.1002/app.53443

Citations: 1

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Abstract

This article offers a fast and innovative process for carrying out in situ polymerization of pyrrole onto a polyester fabric. This process is based on electrically-assisted chemical vapor polymerization that takes around 180 s to produce an electroconductive fabric with a surface resistance of as low as 70 Ω. The ultrasonication carried out at 20 kHz frequency is quite effective in binding the polymer to the fabric. Fourier-transform infrared spectroscopy and X-ray diffraction studies confirm that the polymer formed is polypyrrole. The application of electric potential across an oxidant-enriched fabric results in polymer add-on of polypyrrole as high as 250%. The amount of polypyrrole formed and the surface resistance of the fabric are found to depend on the potential applied across the fabric. The concentrations of the oxidant and the dopant, the time of polymerization, and the rate of monomer vaporization are found to be critical in deciding the surface resistance of the fabric.

Open Research

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Volume140, Issue6

February 10, 2023

e53443

Electrically-assisted chemical vapor polymerization: A novel method for in situ polymerization of pyrrole

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Electrically-assisted chemical vapor polymerization: A novel method for in situ polymerization of pyrrole

Abstract

Open Research

DATA AVAILABILITY STATEMENT

REFERENCES

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