Sustained antioxidant properties of epigallocatechin gallate loaded halloysite for PLA as potentially durable materials
Zhongyang Yao
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (equal), Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Software (equal), Validation (equal), Visualization (lead), Writing - original draft (lead), Writing - review & editing (equal)
Search for more papers by this authorWeiguang Gong
Research and Development Center for Sports Materials, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (supporting), Methodology (supporting), Resources (supporting), Supervision (supporting)
Search for more papers by this authorChenyang Li
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (supporting), Methodology (supporting), Software (supporting), Supervision (supporting), Validation (equal)
Search for more papers by this authorZhaopeng Deng
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (supporting), Methodology (supporting), Software (supporting), Validation (supporting)
Search for more papers by this authorYi Jin
Key Laboratory for Polymerization Engineering and Technology of Ningbo, College of Materials and Chemical Engineering, Ningbo University of Technology (NBUT), Ningbo, China
Contribution: Methodology (supporting)
Search for more papers by this authorCorresponding Author
Xin Meng
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Correspondence
Xin Meng, Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai 200237, China.
Email: [email protected]
Contribution: Conceptualization (equal), Funding acquisition (lead), Methodology (equal), Resources (lead), Supervision (equal), Validation (equal), Writing - review & editing (equal)
Search for more papers by this authorZhongyang Yao
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (equal), Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Software (equal), Validation (equal), Visualization (lead), Writing - original draft (lead), Writing - review & editing (equal)
Search for more papers by this authorWeiguang Gong
Research and Development Center for Sports Materials, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (supporting), Methodology (supporting), Resources (supporting), Supervision (supporting)
Search for more papers by this authorChenyang Li
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (supporting), Methodology (supporting), Software (supporting), Supervision (supporting), Validation (equal)
Search for more papers by this authorZhaopeng Deng
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Contribution: Conceptualization (supporting), Methodology (supporting), Software (supporting), Validation (supporting)
Search for more papers by this authorYi Jin
Key Laboratory for Polymerization Engineering and Technology of Ningbo, College of Materials and Chemical Engineering, Ningbo University of Technology (NBUT), Ningbo, China
Contribution: Methodology (supporting)
Search for more papers by this authorCorresponding Author
Xin Meng
Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai, China
Correspondence
Xin Meng, Shanghai Key Laboratory of Multiphase Material Chemical Engineering, Department of Product Engineering, East China University of Science and Technology, Shanghai 200237, China.
Email: [email protected]
Contribution: Conceptualization (equal), Funding acquisition (lead), Methodology (equal), Resources (lead), Supervision (equal), Validation (equal), Writing - review & editing (equal)
Search for more papers by this authorFunding information: Ningbo Public Welfare Science and Technology Projects, Grant/Award Number: 2021S09
Abstract
Halloysite nanotube (HNT) was etched by hydrochloric acid, and epigallocatechin gallate (EGCG) was loaded into the etched HNT (HH) to prepare loaded antioxidant (HH-E) for polylactic acid (PLA) with improved thermal-oxidative stability. The loading process was confirmed by TGA and FT-IR, and the loading capacity was 16.15%. The presence of EGCG on the surface of etched HNT was further confirmed by nitrogen adsorption and TEM. The effect of loaded EGCG on thermal-oxidative stability of PLA was characterized by the change in OOT values of PLA after the aging process under 140°C. The results showed that HH-E increased OOT values of PLA from 231.2°C to 293.6°C at first, indicating that HH-E provided PLA with excellent thermal-oxidative stability. Furthermore, as can be seen from the trend of OOT changing over aging time, during the 14 days aging process, OOT values of PLA composites with HH-E decreased more slowly than that of PLA composites with EGCG alone, endowing PLA with sustainable thermal-oxidative stability. Further kinetic analysis showed that the apparent activation energy of the degradation process (Ea) of PLA composites with HH-E changed less than that of PLA composites with EGCG alone, which showed that the loading system provided PLA better sustainable stability. Moreover, the isothermal crystallization process of modified PLA was characterized by DSC and POM. The results showed that HH-E provided heterogeneous crystal nucleus for PLA, reducing the half crystallization time (t0.5) and improvement of crystallization rate for PLA. These results prove that HH-E exhibited excellent performance in improving the thermal stability and crystallization property of PLA, showing multifunctional characterization.
Open Research
DATA AVAILABILITY STATEMENT
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| app53411-sup-0001-supinfo.docxWord 2007 document , 696.9 KB | Figure. S1. Oxidation onset temperatures of PLA with different immobilization system. Table S1. Thermogravimetric parameters of EGCG, HH and HH-E Figure S2. (a) Tensile strength and (b) impact strength of PLA, PLA/HH and PLA/HH-E |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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