Article

Fabrication and evaluation of controllable core/shell magnetic molecular imprinted polymers based on konjac glucomannan for trichlorfon

Kai An

School of Chemical and Environmental Engineering, Hubei Minzu University, Enshi, 445000 People's Republic of China

Huiting Kang

Key Laboratory of Biologic Resources Protection and Utilization of Hubei Province, Hubei Minzu University, Enshi, 445000 People's Republic of China

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Dating Tian,

Corresponding Author

Dating Tian

[email protected]

orcid.org/0000-0002-0303-4471

School of Chemical and Environmental Engineering, Hubei Minzu University, Enshi, 445000 People's Republic of China

Key Laboratory of Biologic Resources Protection and Utilization of Hubei Province, Hubei Minzu University, Enshi, 445000 People's Republic of China

Correspondence to: D. Tian (E-mail: [email protected])Search for more papers by this author

Kai An,

Kai An

School of Chemical and Environmental Engineering, Hubei Minzu University, Enshi, 445000 People's Republic of China

Search for more papers by this author

Huiting Kang,

Huiting Kang

Key Laboratory of Biologic Resources Protection and Utilization of Hubei Province, Hubei Minzu University, Enshi, 445000 People's Republic of China

Search for more papers by this author

Dating Tian,

Corresponding Author

Dating Tian

[email protected]

orcid.org/0000-0002-0303-4471

School of Chemical and Environmental Engineering, Hubei Minzu University, Enshi, 445000 People's Republic of China

Key Laboratory of Biologic Resources Protection and Utilization of Hubei Province, Hubei Minzu University, Enshi, 445000 People's Republic of China

Correspondence to: D. Tian (E-mail: [email protected])Search for more papers by this author

First published: 31 December 2019

https://doi.org/10.1002/app.48910

Citations: 6

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ABSTRACT

By combining the controllable core/shell strategy with graft copolymerization of polysaccharides, controllable core/shell magnetic molecularly imprinted polymers (MIPs) based on konjac glucomannan for selective recognition and enrichment of trichlorfon were fabricated and evaluated. By varying the dose of the polymeric precursors, the shell thickness of the core/shell structure could be regulated over a wide range. The magnetic nanoparticles encapsulated by polymers still had high magnetic performance and could be easily separated by an external magnetic field. The results of adsorption experiments showed that the MIPs could specifically recognize and adsorb trichlorfon with excellent selectivity, repeatability, and stability. The adsorption isotherm of MIPs could be fitted by the Langmuir equation. In addition, magnetic MIPs have been successfully applied to the detection of trichlorfon in real samples. Eco-friendly MIPs would be particularly suitable for the enrichment and separation of pesticide residues in food samples. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48910.

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August 10, 2020

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Fabrication and evaluation of controllable core/shell magnetic molecular imprinted polymers based on konjac glucomannan for trichlorfon

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Fabrication and evaluation of controllable core/shell magnetic molecular imprinted polymers based on konjac glucomannan for trichlorfon

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